Precise cooperative sulfur placement leads to semi-crystallinity and selective depolymerisability in CS2/oxetane copolymers
Abstract CS2 promises easy access to degradable sulfur-rich polymers and insights into how main-group derivatisation affects polymer formation and properties, though its ring-opening copolymerisation is plagued by low linkage selectivity and small-molecule by-products. We demonstrate that a cooperat...
Main Authors: | Christoph Fornacon-Wood, Bhargav R. Manjunatha, Merlin R. Stühler, Cesare Gallizioli, Carsten Müller, Patrick Pröhm, Alex J. Plajer |
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Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2023-07-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-023-39951-y |
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