(Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
The title compound, C26H25Cl3N6O4, was prepared by the reaction of (Z)-ethyl 3-amino-3-(4-chlorophenyl)-2-cyanoacrylate and 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride. The dihedral angles between the chlorobenzene and the two pyrazole rings are 59.8 (2) and 33.3&...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809008988 |
| _version_ | 1828854195442155520 |
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| author | Dehua Zhang Xiaoyan Zhang Lijuan Guo |
| author_facet | Dehua Zhang Xiaoyan Zhang Lijuan Guo |
| author_sort | Dehua Zhang |
| collection | DOAJ |
| description | The title compound, C26H25Cl3N6O4, was prepared by the reaction of (Z)-ethyl 3-amino-3-(4-chlorophenyl)-2-cyanoacrylate and 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride. The dihedral angles between the chlorobenzene and the two pyrazole rings are 59.8 (2) and 33.3 (2)°. The two pyrazole rings are oriented to each other at a dihedral angle of 84.7 (2)°. The crystal packing is governed by intermolecular C—H...O interactions, resulting in a three-dimensional network. The ethyl groups are disordered over two positions, with site-occupancy factors of 0.71/0.29 and 0.51/0.49. |
| first_indexed | 2024-12-13T00:28:01Z |
| format | Article |
| id | doaj.art-755241e60f1c4307a52b70d9b45d608e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:28:01Z |
| publishDate | 2009-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-755241e60f1c4307a52b70d9b45d608e2022-12-22T00:05:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654o887o88710.1107/S1600536809008988(Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoateDehua ZhangXiaoyan ZhangLijuan GuoThe title compound, C26H25Cl3N6O4, was prepared by the reaction of (Z)-ethyl 3-amino-3-(4-chlorophenyl)-2-cyanoacrylate and 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride. The dihedral angles between the chlorobenzene and the two pyrazole rings are 59.8 (2) and 33.3 (2)°. The two pyrazole rings are oriented to each other at a dihedral angle of 84.7 (2)°. The crystal packing is governed by intermolecular C—H...O interactions, resulting in a three-dimensional network. The ethyl groups are disordered over two positions, with site-occupancy factors of 0.71/0.29 and 0.51/0.49.http://scripts.iucr.org/cgi-bin/paper?S1600536809008988 |
| spellingShingle | Dehua Zhang Xiaoyan Zhang Lijuan Guo (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate Acta Crystallographica Section E |
| title | (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate |
| title_full | (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate |
| title_fullStr | (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate |
| title_full_unstemmed | (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate |
| title_short | (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate |
| title_sort | z ethyl 3 bis 4 chloro 3 ethyl 1 methyl 1h pyrazol 5 ylcarbonyl amino 3 4 chlorophenyl 2 cyanopropanoate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809008988 |
| work_keys_str_mv | AT dehuazhang zethyl3bis4chloro3ethyl1methyl1hpyrazol5ylcarbonylamino34chlorophenyl2cyanopropanoate AT xiaoyanzhang zethyl3bis4chloro3ethyl1methyl1hpyrazol5ylcarbonylamino34chlorophenyl2cyanopropanoate AT lijuanguo zethyl3bis4chloro3ethyl1methyl1hpyrazol5ylcarbonylamino34chlorophenyl2cyanopropanoate |