(5Z)-5-(2-Hydroxybenzylidene)-2-thioxo-1,3-thiazolidin-4-one methanol hemisolvate
In the title compound, C10H7NO2S2·0.5CH3OH, the dihedral angle between the aromatic rings is 11.43 (11)° and a short intramolecular C—H...S contact occurs. The methanol solvent molecule is equally disordered over two sets of sites. In the crystal...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809039555 |
| Summary: | In the title compound, C10H7NO2S2·0.5CH3OH, the dihedral angle between the aromatic rings is 11.43 (11)° and a short intramolecular C—H...S contact occurs. The methanol solvent molecule is equally disordered over two sets of sites. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds occur. The methanol solvent molecule connects the dimers through O—H...S and O—H...O intermolecular hydrogen bonds. Further stability is afforded by C—H...π and π–π interactions [centroid–centroid separation = 3.5948 (13) Å]. |
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| ISSN: | 1600-5368 |