Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)
In the title compound, [(tBuSiMe2O)2MoO2(2,2′-bipyridine)] or [Mo(C6H15OSi)2O2(C10H8N2)], the MoVI atom has a distorted octahedral environment with the siloxy substituents occupying the trans positions. The complex contains a rare (R3SiO)2MO2 (M = Mo, W) structural motif and was formed in a reaction...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018008472 |
| _version_ | 1819003678846091264 |
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| author | Mikhail E. Minyaev Alexander A. Vinogradov Ilya E. Nifant'ev Andrei V. Churakov |
| author_facet | Mikhail E. Minyaev Alexander A. Vinogradov Ilya E. Nifant'ev Andrei V. Churakov |
| author_sort | Mikhail E. Minyaev |
| collection | DOAJ |
| description | In the title compound, [(tBuSiMe2O)2MoO2(2,2′-bipyridine)] or [Mo(C6H15OSi)2O2(C10H8N2)], the MoVI atom has a distorted octahedral environment with the siloxy substituents occupying the trans positions. The complex contains a rare (R3SiO)2MO2 (M = Mo, W) structural motif and was formed in a reaction between sodium molybdate and tert-butyldimethylsilyl chloride in the presence of 2,2-bipyridine. In the crystal, neighbouring molecules are linked by C—H...O=Mo hydrogen bonds, forming chains propagating along the a-axis direction. |
| first_indexed | 2024-12-20T23:24:49Z |
| format | Article |
| id | doaj.art-757d19790c97495d808dea7393d5a64c |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:24:49Z |
| publishDate | 2018-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-757d19790c97495d808dea7393d5a64c2022-12-21T19:23:25ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-07-0174797097210.1107/S2056989018008472su5447Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)Mikhail E. Minyaev0Alexander A. Vinogradov1Ilya E. Nifant'ev2Andrei V. Churakov3A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991, Moscow, Russian FederationA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991, Moscow, Russian FederationA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991, Moscow, Russian FederationN.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prospect, Moscow 119991, Russian FederationIn the title compound, [(tBuSiMe2O)2MoO2(2,2′-bipyridine)] or [Mo(C6H15OSi)2O2(C10H8N2)], the MoVI atom has a distorted octahedral environment with the siloxy substituents occupying the trans positions. The complex contains a rare (R3SiO)2MO2 (M = Mo, W) structural motif and was formed in a reaction between sodium molybdate and tert-butyldimethylsilyl chloride in the presence of 2,2-bipyridine. In the crystal, neighbouring molecules are linked by C—H...O=Mo hydrogen bonds, forming chains propagating along the a-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2056989018008472crystal structuremolybdenum(VI)rare structural motifcoordination compoundsNMRhydrogen bonding. |
| spellingShingle | Mikhail E. Minyaev Alexander A. Vinogradov Ilya E. Nifant'ev Andrei V. Churakov Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) Acta Crystallographica Section E: Crystallographic Communications crystal structure molybdenum(VI) rare structural motif coordination compounds NMR hydrogen bonding. |
| title | Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) |
| title_full | Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) |
| title_fullStr | Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) |
| title_full_unstemmed | Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) |
| title_short | Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) |
| title_sort | crystal structure of 2 2 bipyridine κ2n n trans bis tert butyldimethylsilyloxy cis dioxidomolybdenum vi |
| topic | crystal structure molybdenum(VI) rare structural motif coordination compounds NMR hydrogen bonding. |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989018008472 |
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