Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys

The tribological behavior of hot-rolled and boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> high-entropy alloys (HEAs) sliding against a Si<sub>3</sub>N<sub>4</sub> ball was investigated in the air, deioni...

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Main Authors: Xin Guo, Xi Jin, Xiaohui Shi, Huijun Yang, Min Zhang, Junwei Qiao
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/11/10/1561
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author Xin Guo
Xi Jin
Xiaohui Shi
Huijun Yang
Min Zhang
Junwei Qiao
author_facet Xin Guo
Xi Jin
Xiaohui Shi
Huijun Yang
Min Zhang
Junwei Qiao
author_sort Xin Guo
collection DOAJ
description The tribological behavior of hot-rolled and boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> high-entropy alloys (HEAs) sliding against a Si<sub>3</sub>N<sub>4</sub> ball was investigated in the air, deionized water and seawater. The results showed that the hot-rolled Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> HEA was composed of an FCC (face-centered cubic) phase. In addition, the boronized HEA was composed of a great number of borides, including CrB, FeB, MnB, Fe<sub>2</sub>B, Fe<sub>3</sub>B and MnB<sub>2</sub>. The hardness increased from 139 HV to 970 HV after boronizing. In air, the wear rate decreased from 4.51 × 10<sup>−4</sup> mm<sup>3</sup>/Nm to 0.72 × 10<sup>−4</sup> mm<sup>3</sup>/Nm after boronizing. The wear mechanism transformed from abrasive wear and oxidative wear to the polishing effect. After boronizing, in the deionized water, the wear rate decreased from 1.27 × 10<sup>−4</sup> mm<sup>3</sup>/Nm to 8.43 × 10<sup>−5</sup> mm<sup>3</sup>/Nm. The wear mechanism transformed from abrasive wear and delamination wear to delamination wear. In the seawater, the wear rate decreased by about ten times that of hot-rolled alloy.
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spelling doaj.art-757df6e019d543d3b5e9ca11775feee52023-11-22T19:08:41ZengMDPI AGMetals2075-47012021-09-011110156110.3390/met11101561Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy AlloysXin Guo0Xi Jin1Xiaohui Shi2Huijun Yang3Min Zhang4Junwei Qiao5College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaCollege of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaCollege of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaCollege of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaCollege of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaCollege of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, ChinaThe tribological behavior of hot-rolled and boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> high-entropy alloys (HEAs) sliding against a Si<sub>3</sub>N<sub>4</sub> ball was investigated in the air, deionized water and seawater. The results showed that the hot-rolled Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> HEA was composed of an FCC (face-centered cubic) phase. In addition, the boronized HEA was composed of a great number of borides, including CrB, FeB, MnB, Fe<sub>2</sub>B, Fe<sub>3</sub>B and MnB<sub>2</sub>. The hardness increased from 139 HV to 970 HV after boronizing. In air, the wear rate decreased from 4.51 × 10<sup>−4</sup> mm<sup>3</sup>/Nm to 0.72 × 10<sup>−4</sup> mm<sup>3</sup>/Nm after boronizing. The wear mechanism transformed from abrasive wear and oxidative wear to the polishing effect. After boronizing, in the deionized water, the wear rate decreased from 1.27 × 10<sup>−4</sup> mm<sup>3</sup>/Nm to 8.43 × 10<sup>−5</sup> mm<sup>3</sup>/Nm. The wear mechanism transformed from abrasive wear and delamination wear to delamination wear. In the seawater, the wear rate decreased by about ten times that of hot-rolled alloy.https://www.mdpi.com/2075-4701/11/10/1561high-entropy alloysboronizedwearoxidationlubricate
spellingShingle Xin Guo
Xi Jin
Xiaohui Shi
Huijun Yang
Min Zhang
Junwei Qiao
Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys
Metals
high-entropy alloys
boronized
wear
oxidation
lubricate
title Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys
title_full Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys
title_fullStr Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys
title_full_unstemmed Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys
title_short Tribological Behavior of Boronized Fe<sub>40</sub>Mn<sub>20</sub>Cr<sub>20</sub>Ni<sub>20</sub> High-Entropy Alloys
title_sort tribological behavior of boronized fe sub 40 sub mn sub 20 sub cr sub 20 sub ni sub 20 sub high entropy alloys
topic high-entropy alloys
boronized
wear
oxidation
lubricate
url https://www.mdpi.com/2075-4701/11/10/1561
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