Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions
The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which...
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| Format: | Article |
| Language: | English |
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MDPI AG
2018-07-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/8/8/309 |
| _version_ | 1811187392900497408 |
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| author | Augusto Rivera Jicli José Rojas Jaime Ríos-Motta Michael Bolte |
| author_facet | Augusto Rivera Jicli José Rojas Jaime Ríos-Motta Michael Bolte |
| author_sort | Augusto Rivera |
| collection | DOAJ |
| description | The synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper. |
| first_indexed | 2024-04-11T14:02:41Z |
| format | Article |
| id | doaj.art-7594fb1ca30343a48d11012549c266f9 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T14:02:41Z |
| publishDate | 2018-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-7594fb1ca30343a48d11012549c266f92022-12-22T04:20:03ZengMDPI AGCrystals2073-43522018-07-018830910.3390/cryst8080309cryst8080309Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding InteractionsAugusto Rivera0Jicli José Rojas1Jaime Ríos-Motta2Michael Bolte3Departamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Sede Bogotá, Carrera 30 No. 45-03, Bogotá, Código Postal 111321, ColombiaDepartamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Sede Bogotá, Carrera 30 No. 45-03, Bogotá, Código Postal 111321, ColombiaDepartamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Sede Bogotá, Carrera 30 No. 45-03, Bogotá, Código Postal 111321, ColombiaInstitut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von Laue-Str., 7, 60438 Frankfurt/Main, GermanyThe synthesis and single crystal structure of a new cocrystal, which is composed of OHphenolic∙∙∙OHphenolic∙∙∙Naminalic supramolecular heterosynthons assembled from 4-tert-butylphenol and the macrocyclic aminal TATU, is presented. This cocrystal was prepared by solvent-free assisted grinding, which is a commonly used mechanochemical method. Crystal structure, supramolecular assembly through hydrogen bonding interactions as well as the physical and spectroscopic properties of the title cocrystal are presented in this paper.http://www.mdpi.com/2073-4352/8/8/309supramolecular chemistrycrystal engineeringcocrystalshydrogen bondsnoncovalent interactionsaminal structure |
| spellingShingle | Augusto Rivera Jicli José Rojas Jaime Ríos-Motta Michael Bolte Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions Crystals supramolecular chemistry crystal engineering cocrystals hydrogen bonds noncovalent interactions aminal structure |
| title | Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions |
| title_full | Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions |
| title_fullStr | Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions |
| title_full_unstemmed | Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions |
| title_short | Mechanochemical Synthesis of a Cocrystal of Two Supramolecular Hydrogen-Bonded Aggregates of 1,3,6,8-Tetraazatricyclo[4.3.1.13,8]undecane (TATU) with 4-tert-Butylphenol Bearing Different Hydrogen Bonding Interactions |
| title_sort | mechanochemical synthesis of a cocrystal of two supramolecular hydrogen bonded aggregates of 1 3 6 8 tetraazatricyclo 4 3 1 13 8 undecane tatu with 4 tert butylphenol bearing different hydrogen bonding interactions |
| topic | supramolecular chemistry crystal engineering cocrystals hydrogen bonds noncovalent interactions aminal structure |
| url | http://www.mdpi.com/2073-4352/8/8/309 |
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