Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt
Abstract A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2022-12-01
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| Series: | ChemistryOpen |
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| Online Access: | https://doi.org/10.1002/open.202200233 |
| _version_ | 1797954173252141056 |
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| author | Assist. Prof. Dr. Saima Anjum Assoc. Prof. Dr. Baohua Lou Amiza Tahir Prof. Dr. Aziz‐ur‐Rehman Assist. Prof. Dr. M. Rehan H. Shah Gilani Prof. Dr. Guobao Xu |
| author_facet | Assist. Prof. Dr. Saima Anjum Assoc. Prof. Dr. Baohua Lou Amiza Tahir Prof. Dr. Aziz‐ur‐Rehman Assist. Prof. Dr. M. Rehan H. Shah Gilani Prof. Dr. Guobao Xu |
| author_sort | Assist. Prof. Dr. Saima Anjum |
| collection | DOAJ |
| description | Abstract A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10−9 m, and broad linearity of 0.1 to 1000 μm were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine. |
| first_indexed | 2024-04-10T23:14:29Z |
| format | Article |
| id | doaj.art-7599b13b170b48fa9a8073b01d3ae4a7 |
| institution | Directory Open Access Journal |
| issn | 2191-1363 |
| language | English |
| last_indexed | 2024-04-10T23:14:29Z |
| publishDate | 2022-12-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemistryOpen |
| spelling | doaj.art-7599b13b170b48fa9a8073b01d3ae4a72023-01-13T01:50:53ZengWiley-VCHChemistryOpen2191-13632022-12-011112n/an/a10.1002/open.202200233Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium SaltAssist. Prof. Dr. Saima Anjum0Assoc. Prof. Dr. Baohua Lou1Amiza Tahir2Prof. Dr. Aziz‐ur‐Rehman3Assist. Prof. Dr. M. Rehan H. Shah Gilani4Prof. Dr. Guobao Xu5State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin 130022 P.R. ChinaState Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin 130022 P.R. ChinaDepartment of Chemistry Govt. Sadiq College Women University Bahawalpur PakistanState Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin 130022 P.R. ChinaInstitute of Chemical Sciences Bahauddin Zakariya University Multan 60800 PakistanState Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun Jilin 130022 P.R. ChinaAbstract A glassy carbon electrode (GCE) has been modified by an in situ electrochemical reduction of an aryldiazonium salt generated from the reaction of 4‐aminobenzoic acid and sodium nitrite in acidic ethanolic solution. The as‐prepared phenyl carboxylic acid‐modified glassy carbon electrode has been, for the first time, used for the electrochemical determination of dopamine. Under optimal experimental parameters, outstanding electrocatalytic activity, high sensitivity at a LOD of 5.6×10−9 m, and broad linearity of 0.1 to 1000 μm were obtained. The crafted electrochemical platform demonstrated excellent stability, specificity, and anti‐interference capability towards the sensing of dopamine.https://doi.org/10.1002/open.202200233ascorbic acidchemically modified electrodediazoniumdopamine analysiselectrochemical sensing |
| spellingShingle | Assist. Prof. Dr. Saima Anjum Assoc. Prof. Dr. Baohua Lou Amiza Tahir Prof. Dr. Aziz‐ur‐Rehman Assist. Prof. Dr. M. Rehan H. Shah Gilani Prof. Dr. Guobao Xu Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt ChemistryOpen ascorbic acid chemically modified electrode diazonium dopamine analysis electrochemical sensing |
| title | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
| title_full | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
| title_fullStr | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
| title_full_unstemmed | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
| title_short | Electrochemical Detection of Dopamine using a Phenyl Carboxylic Acid‐Functionalized Electrode Made by Electrochemical Reduction of a Diazonium Salt |
| title_sort | electrochemical detection of dopamine using a phenyl carboxylic acid functionalized electrode made by electrochemical reduction of a diazonium salt |
| topic | ascorbic acid chemically modified electrode diazonium dopamine analysis electrochemical sensing |
| url | https://doi.org/10.1002/open.202200233 |
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