Adsorption of congo red using kaolinite-cellulose adsorbent

Kaolinite was impregnated with cellulose extracted from rubber wood fibers has been done. The product of impregnated kaolinite-cellulose was characterized using FT-IR spectrophotometer. Furthermore, the impregnation results are used as an adsorbent of Congo red. Adsorption of Congo red was also stud...

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Main Authors: Santa Oktavia Ginting, Risfidian Mohadi
Format: Article
Language:English
Published: Magister Program of Material Sciences, Graduate School of Universitas Sriwijaya 2017-04-01
Series:Science and Technology Indonesia
Online Access:http://sciencetechindonesia.com/index.php/jsti/article/view/13
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author Santa Oktavia Ginting
Risfidian Mohadi
author_facet Santa Oktavia Ginting
Risfidian Mohadi
author_sort Santa Oktavia Ginting
collection DOAJ
description Kaolinite was impregnated with cellulose extracted from rubber wood fibers has been done. The product of impregnated kaolinite-cellulose was characterized using FT-IR spectrophotometer. Furthermore, the impregnation results are used as an adsorbent of Congo red. Adsorption of Congo red was also studied the kinetic and thermodynamic parameters. The results of characterization using FT-IR spectrophotometer shows the process of impregnation was successfully conducted. It was indicated that the presence wavenumber at 910.4 - 918.12 cm-1 and 1033.85 cm-1 become 1026.13 cm-1 and the existence of vibration at wavenumber 2931.8 cm-1. The pH of adsorption was adjusted to 4 before the adsorption process. The adsorption process of cellulose impregnated kaolinite shows the rate of adsorption (k) of 0.002 min-1, the adsorption reviews largest capacity (b) at 50 °C was 500 mol/g. The greatest adsorption energy (E) at 40 °C is 11:09 kJ/mol. The enthalpy value (ΔH) and entropy (ΔS) decreased with increasing Congo red dye concentration. Keywords: kaolinite, cellulose, impregnation, Congo red
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spelling doaj.art-75ae31c664f34324a05f79623f74d3812024-03-02T08:27:27ZengMagister Program of Material Sciences, Graduate School of Universitas SriwijayaScience and Technology Indonesia2580-44052580-43912017-04-0122293610.26554/sti.2017.2.2.29-3613Adsorption of congo red using kaolinite-cellulose adsorbentSanta Oktavia GintingRisfidian MohadiKaolinite was impregnated with cellulose extracted from rubber wood fibers has been done. The product of impregnated kaolinite-cellulose was characterized using FT-IR spectrophotometer. Furthermore, the impregnation results are used as an adsorbent of Congo red. Adsorption of Congo red was also studied the kinetic and thermodynamic parameters. The results of characterization using FT-IR spectrophotometer shows the process of impregnation was successfully conducted. It was indicated that the presence wavenumber at 910.4 - 918.12 cm-1 and 1033.85 cm-1 become 1026.13 cm-1 and the existence of vibration at wavenumber 2931.8 cm-1. The pH of adsorption was adjusted to 4 before the adsorption process. The adsorption process of cellulose impregnated kaolinite shows the rate of adsorption (k) of 0.002 min-1, the adsorption reviews largest capacity (b) at 50 °C was 500 mol/g. The greatest adsorption energy (E) at 40 °C is 11:09 kJ/mol. The enthalpy value (ΔH) and entropy (ΔS) decreased with increasing Congo red dye concentration. Keywords: kaolinite, cellulose, impregnation, Congo redhttp://sciencetechindonesia.com/index.php/jsti/article/view/13
spellingShingle Santa Oktavia Ginting
Risfidian Mohadi
Adsorption of congo red using kaolinite-cellulose adsorbent
Science and Technology Indonesia
title Adsorption of congo red using kaolinite-cellulose adsorbent
title_full Adsorption of congo red using kaolinite-cellulose adsorbent
title_fullStr Adsorption of congo red using kaolinite-cellulose adsorbent
title_full_unstemmed Adsorption of congo red using kaolinite-cellulose adsorbent
title_short Adsorption of congo red using kaolinite-cellulose adsorbent
title_sort adsorption of congo red using kaolinite cellulose adsorbent
url http://sciencetechindonesia.com/index.php/jsti/article/view/13
work_keys_str_mv AT santaoktaviaginting adsorptionofcongoredusingkaolinitecelluloseadsorbent
AT risfidianmohadi adsorptionofcongoredusingkaolinitecelluloseadsorbent