Room-temperature thermally induced relaxation effect in a two-dimensional cyano-bridged Cu-Mo bimetal assembly and thermodynamic analysis of the relaxation process

We observed a photo-switching effect in [CuII(1,4,8,11-tetraazacyclodecane)]2[MoIV(CN)8]·10H2O by irradiation with 410-nm light around room temperature using infrared spectroscopy. This photo-switching is caused by the photo-induced charge transfer from MoIV to CuII. The photo-induced phase thermall...

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Bibliographic Details
Main Authors: Yoshikazu Umeta, Hiroko Tokoro, Noriaki Ozaki, Shin-ichi Ohkoshi
Format: Article
Language:English
Published: AIP Publishing LLC 2013-04-01
Series:AIP Advances
Online Access:http://link.aip.org/link/doi/10.1063/1.4802970

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