The Valence and Spin State Tuning of Iron(II/III) Porphyrazines with Bulky Pyrrolyl Periphery in Solution and Solid State

The Valence and Spin State Tuning of Iron(II/III) Porphyrazines with Bulky Pyrrolyl Periphery in Solution and Solid State

Iron(III) porphyrazines containing peripheral 2,5-dimethyl-, 2-methyl-5-phenyl-, and 2,3,5-triphenyl-1<i>H</i>-pyrrol-1-yl substituents were synthesized and subjected to physicochemical characterization. This was accomplished by high-resolution mass spectrometry, nuclear magnetic resonan...

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Bibliographic Details
Main Authors: Tomasz Koczorowski, Wojciech Szczolko, Pawel Bakun, Barbara Wicher, Lukasz Sobotta, Maria Gdaniec, Anna Teubert, Jadwiga Mielcarek, Ewa Tykarska, Jozef Korecki, Kvetoslava Burda, Tomasz Goslinski
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Molecules
Subjects:
porphyrazine
crystal structure
Mössbauer spectroscopy
iron valence and spin state
Online Access:https://www.mdpi.com/1420-3049/27/22/7820

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