Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes

We demonstrate that electrolyte-gated organic field-effect transistors (EGOFETs) can detect extremely minute modifications in the composition of the electrochemical double layers forming at the channel/electrolyte and gate/electrolyte interfaces, thus permitting real-time monitoring of alkylthiols s...

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Main Authors: Alexandra Tibaldi, Laure Fillaud, Guillaume Anquetin, Marion Woytasik, Samia Zrig, Benoît Piro, Giorgio Mattana, Vincent Noël
Format: Article
Language:English
Published: Elsevier 2019-01-01
Series:Electrochemistry Communications
Online Access:http://www.sciencedirect.com/science/article/pii/S1388248118302753
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author Alexandra Tibaldi
Laure Fillaud
Guillaume Anquetin
Marion Woytasik
Samia Zrig
Benoît Piro
Giorgio Mattana
Vincent Noël
author_facet Alexandra Tibaldi
Laure Fillaud
Guillaume Anquetin
Marion Woytasik
Samia Zrig
Benoît Piro
Giorgio Mattana
Vincent Noël
author_sort Alexandra Tibaldi
collection DOAJ
description We demonstrate that electrolyte-gated organic field-effect transistors (EGOFETs) can detect extremely minute modifications in the composition of the electrochemical double layers forming at the channel/electrolyte and gate/electrolyte interfaces, thus permitting real-time monitoring of alkylthiols self-assembling on a gold surface. We used this property to assay the enzymatic activity of acetylcholinesterase which, in the presence of its substrate (acetylthiocholine), produces thiocholine. Keywords: Electrochemical double layer, EGOFET, Alkylthiol, Acetylcholinesterase
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spelling doaj.art-75bc1bbffd854be09f623041e01b17192022-12-21T20:04:34ZengElsevierElectrochemistry Communications1388-24812019-01-01984346Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processesAlexandra Tibaldi0Laure Fillaud1Guillaume Anquetin2Marion Woytasik3Samia Zrig4Benoît Piro5Giorgio Mattana6Vincent Noël7University of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity Paris-Saclay, Centre for Nanoscience and Nanotechnology, CNRS UMR 9001, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, France; Corresponding author.We demonstrate that electrolyte-gated organic field-effect transistors (EGOFETs) can detect extremely minute modifications in the composition of the electrochemical double layers forming at the channel/electrolyte and gate/electrolyte interfaces, thus permitting real-time monitoring of alkylthiols self-assembling on a gold surface. We used this property to assay the enzymatic activity of acetylcholinesterase which, in the presence of its substrate (acetylthiocholine), produces thiocholine. Keywords: Electrochemical double layer, EGOFET, Alkylthiol, Acetylcholinesterasehttp://www.sciencedirect.com/science/article/pii/S1388248118302753
spellingShingle Alexandra Tibaldi
Laure Fillaud
Guillaume Anquetin
Marion Woytasik
Samia Zrig
Benoît Piro
Giorgio Mattana
Vincent Noël
Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
Electrochemistry Communications
title Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
title_full Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
title_fullStr Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
title_full_unstemmed Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
title_short Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
title_sort electrolyte gated organic field effect transistors egofets as complementary tools to electrochemistry for the study of surface processes
url http://www.sciencedirect.com/science/article/pii/S1388248118302753
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