Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes
We demonstrate that electrolyte-gated organic field-effect transistors (EGOFETs) can detect extremely minute modifications in the composition of the electrochemical double layers forming at the channel/electrolyte and gate/electrolyte interfaces, thus permitting real-time monitoring of alkylthiols s...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2019-01-01
|
Series: | Electrochemistry Communications |
Online Access: | http://www.sciencedirect.com/science/article/pii/S1388248118302753 |
_version_ | 1818906802986680320 |
---|---|
author | Alexandra Tibaldi Laure Fillaud Guillaume Anquetin Marion Woytasik Samia Zrig Benoît Piro Giorgio Mattana Vincent Noël |
author_facet | Alexandra Tibaldi Laure Fillaud Guillaume Anquetin Marion Woytasik Samia Zrig Benoît Piro Giorgio Mattana Vincent Noël |
author_sort | Alexandra Tibaldi |
collection | DOAJ |
description | We demonstrate that electrolyte-gated organic field-effect transistors (EGOFETs) can detect extremely minute modifications in the composition of the electrochemical double layers forming at the channel/electrolyte and gate/electrolyte interfaces, thus permitting real-time monitoring of alkylthiols self-assembling on a gold surface. We used this property to assay the enzymatic activity of acetylcholinesterase which, in the presence of its substrate (acetylthiocholine), produces thiocholine. Keywords: Electrochemical double layer, EGOFET, Alkylthiol, Acetylcholinesterase |
first_indexed | 2024-12-19T21:45:01Z |
format | Article |
id | doaj.art-75bc1bbffd854be09f623041e01b1719 |
institution | Directory Open Access Journal |
issn | 1388-2481 |
language | English |
last_indexed | 2024-12-19T21:45:01Z |
publishDate | 2019-01-01 |
publisher | Elsevier |
record_format | Article |
series | Electrochemistry Communications |
spelling | doaj.art-75bc1bbffd854be09f623041e01b17192022-12-21T20:04:34ZengElsevierElectrochemistry Communications1388-24812019-01-01984346Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processesAlexandra Tibaldi0Laure Fillaud1Guillaume Anquetin2Marion Woytasik3Samia Zrig4Benoît Piro5Giorgio Mattana6Vincent Noël7University of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity Paris-Saclay, Centre for Nanoscience and Nanotechnology, CNRS UMR 9001, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, FranceUniversity of Paris, ITODYS, CNRS UMR 7086, France; Corresponding author.We demonstrate that electrolyte-gated organic field-effect transistors (EGOFETs) can detect extremely minute modifications in the composition of the electrochemical double layers forming at the channel/electrolyte and gate/electrolyte interfaces, thus permitting real-time monitoring of alkylthiols self-assembling on a gold surface. We used this property to assay the enzymatic activity of acetylcholinesterase which, in the presence of its substrate (acetylthiocholine), produces thiocholine. Keywords: Electrochemical double layer, EGOFET, Alkylthiol, Acetylcholinesterasehttp://www.sciencedirect.com/science/article/pii/S1388248118302753 |
spellingShingle | Alexandra Tibaldi Laure Fillaud Guillaume Anquetin Marion Woytasik Samia Zrig Benoît Piro Giorgio Mattana Vincent Noël Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes Electrochemistry Communications |
title | Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes |
title_full | Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes |
title_fullStr | Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes |
title_full_unstemmed | Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes |
title_short | Electrolyte-gated organic field-effect transistors (EGOFETs) as complementary tools to electrochemistry for the study of surface processes |
title_sort | electrolyte gated organic field effect transistors egofets as complementary tools to electrochemistry for the study of surface processes |
url | http://www.sciencedirect.com/science/article/pii/S1388248118302753 |
work_keys_str_mv | AT alexandratibaldi electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT laurefillaud electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT guillaumeanquetin electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT marionwoytasik electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT samiazrig electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT benoitpiro electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT giorgiomattana electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses AT vincentnoel electrolytegatedorganicfieldeffecttransistorsegofetsascomplementarytoolstoelectrochemistryforthestudyofsurfaceprocesses |