Thermodynamics of an Empty Box

A gas in a box is perhaps the most important model system studied in thermodynamics and statistical mechanics. Usually, studies focus on the gas, whereas the box merely serves as an idealized confinement. The present article focuses on the box as the central object and develops a thermodynamic theor...

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Main Authors: Georg J. Schmitz, Michael te Vrugt, Tore Haug-Warberg, Lodin Ellingsen, Paul Needham, Raphael Wittkowski
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/25/2/315
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author Georg J. Schmitz
Michael te Vrugt
Tore Haug-Warberg
Lodin Ellingsen
Paul Needham
Raphael Wittkowski
author_facet Georg J. Schmitz
Michael te Vrugt
Tore Haug-Warberg
Lodin Ellingsen
Paul Needham
Raphael Wittkowski
author_sort Georg J. Schmitz
collection DOAJ
description A gas in a box is perhaps the most important model system studied in thermodynamics and statistical mechanics. Usually, studies focus on the gas, whereas the box merely serves as an idealized confinement. The present article focuses on the box as the central object and develops a thermodynamic theory by treating the geometric degrees of freedom of the box as the degrees of freedom of a thermodynamic system. Applying standard mathematical methods to the thermodynamics of an empty box allows equations with the same structure as those of cosmology and classical and quantum mechanics to be derived. The simple model system of an empty box is shown to have interesting connections to classical mechanics, special relativity, and quantum field theory.
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spelling doaj.art-75ca8757ada24935b7ac5b3f45c4e4122023-11-16T20:23:47ZengMDPI AGEntropy1099-43002023-02-0125231510.3390/e25020315Thermodynamics of an Empty BoxGeorg J. Schmitz0Michael te Vrugt1Tore Haug-Warberg2Lodin Ellingsen3Paul Needham4Raphael Wittkowski5MICRESS Group, ACCESS e.V., Intzestr. 5, D-52072 Aachen, GermanyInstitut für Theoretische Physik, Center for Soft Nanoscience, Westfälische Wilhelms-Universität Münster, D-48149 Münster, GermanyDepartment of Chemical Engineering, Norwegian University of Science and Technology (NTNU), N-7491 Trondheim, NorwayDepartment of Chemical Engineering, Norwegian University of Science and Technology (NTNU), N-7491 Trondheim, NorwayDepartment of Philosophy, University of Stockholm, SE-106 91 Stockholm, SwedenInstitut für Theoretische Physik, Center for Soft Nanoscience, Westfälische Wilhelms-Universität Münster, D-48149 Münster, GermanyA gas in a box is perhaps the most important model system studied in thermodynamics and statistical mechanics. Usually, studies focus on the gas, whereas the box merely serves as an idealized confinement. The present article focuses on the box as the central object and develops a thermodynamic theory by treating the geometric degrees of freedom of the box as the degrees of freedom of a thermodynamic system. Applying standard mathematical methods to the thermodynamics of an empty box allows equations with the same structure as those of cosmology and classical and quantum mechanics to be derived. The simple model system of an empty box is shown to have interesting connections to classical mechanics, special relativity, and quantum field theory.https://www.mdpi.com/1099-4300/25/2/315Euler homogeneityUnruh temperatureanisotropic Hubble parameterquantized spaceLorentz factorblack-hole entropy
spellingShingle Georg J. Schmitz
Michael te Vrugt
Tore Haug-Warberg
Lodin Ellingsen
Paul Needham
Raphael Wittkowski
Thermodynamics of an Empty Box
Entropy
Euler homogeneity
Unruh temperature
anisotropic Hubble parameter
quantized space
Lorentz factor
black-hole entropy
title Thermodynamics of an Empty Box
title_full Thermodynamics of an Empty Box
title_fullStr Thermodynamics of an Empty Box
title_full_unstemmed Thermodynamics of an Empty Box
title_short Thermodynamics of an Empty Box
title_sort thermodynamics of an empty box
topic Euler homogeneity
Unruh temperature
anisotropic Hubble parameter
quantized space
Lorentz factor
black-hole entropy
url https://www.mdpi.com/1099-4300/25/2/315
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AT lodinellingsen thermodynamicsofanemptybox
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AT raphaelwittkowski thermodynamicsofanemptybox