Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation

The possibility of controlled scalable nanostructuring of surfaces by the formation of the plasmonic nanoparticles is very important for the development of sensors, solar cells, etc. In this work, the formation of the ensembles of silver nanoparticles on silicon and glass substrates by the magnetron...

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Main Authors: Oleg Streletskiy, Ilya Zavidovskiy, Dmitry Yakubovsky, Natalia Doroshina, Alexander Syuy, Yury Lebedinskij, Andrey Markeev, Aleksey Arsenin, Valentyn Volkov, Sergey Novikov
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/21/7721
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author Oleg Streletskiy
Ilya Zavidovskiy
Dmitry Yakubovsky
Natalia Doroshina
Alexander Syuy
Yury Lebedinskij
Andrey Markeev
Aleksey Arsenin
Valentyn Volkov
Sergey Novikov
author_facet Oleg Streletskiy
Ilya Zavidovskiy
Dmitry Yakubovsky
Natalia Doroshina
Alexander Syuy
Yury Lebedinskij
Andrey Markeev
Aleksey Arsenin
Valentyn Volkov
Sergey Novikov
author_sort Oleg Streletskiy
collection DOAJ
description The possibility of controlled scalable nanostructuring of surfaces by the formation of the plasmonic nanoparticles is very important for the development of sensors, solar cells, etc. In this work, the formation of the ensembles of silver nanoparticles on silicon and glass substrates by the magnetron deposition technique and the subsequent low-energy Ar<sup>+</sup> ion irradiation was studied. The possibility of controlling the sizes, shapes and aerial density of the nanoparticles by the variation of the deposition and irradiation parameters was systematically investigated. Scanning electron microscopy studies of the samples deposited and irradiated in different conditions allowed for analysis of the morphological features of the nanoparticles and the distribution of their sizes and allowed for determination of the optimal parameters for the formation of the plasmonic-active structures. Additionally, the plasmonic properties of the resulting nanoparticles were characterized by means of linear spectroscopy and surface-enhanced Raman spectroscopy. Hereby, in this work, we demonstrate the possibility of the fabrication of silver nanoparticles with a widely varied range of average sizes and aerial density by means of a post-deposition ion irradiation technique to form nanostructured surfaces which can be applied in sensing technologies and surface-enhanced Raman spectroscopy (SERS).
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spelling doaj.art-75d5d1b79448482895a9db8567da80832023-11-24T05:39:45ZengMDPI AGMaterials1996-19442022-11-011521772110.3390/ma15217721Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam IrradiationOleg Streletskiy0Ilya Zavidovskiy1Dmitry Yakubovsky2Natalia Doroshina3Alexander Syuy4Yury Lebedinskij5Andrey Markeev6Aleksey Arsenin7Valentyn Volkov8Sergey Novikov9Department of Physics, M.V. Lomonosov Moscow State University, Leninskie Gory 1, 119991 Moscow, RussiaDepartment of Physics, M.V. Lomonosov Moscow State University, Leninskie Gory 1, 119991 Moscow, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaCenter for Photonics and 2D Materials, Moscow Institute of Physics and Technology, 141700 Dolgoprudny, RussiaThe possibility of controlled scalable nanostructuring of surfaces by the formation of the plasmonic nanoparticles is very important for the development of sensors, solar cells, etc. In this work, the formation of the ensembles of silver nanoparticles on silicon and glass substrates by the magnetron deposition technique and the subsequent low-energy Ar<sup>+</sup> ion irradiation was studied. The possibility of controlling the sizes, shapes and aerial density of the nanoparticles by the variation of the deposition and irradiation parameters was systematically investigated. Scanning electron microscopy studies of the samples deposited and irradiated in different conditions allowed for analysis of the morphological features of the nanoparticles and the distribution of their sizes and allowed for determination of the optimal parameters for the formation of the plasmonic-active structures. Additionally, the plasmonic properties of the resulting nanoparticles were characterized by means of linear spectroscopy and surface-enhanced Raman spectroscopy. Hereby, in this work, we demonstrate the possibility of the fabrication of silver nanoparticles with a widely varied range of average sizes and aerial density by means of a post-deposition ion irradiation technique to form nanostructured surfaces which can be applied in sensing technologies and surface-enhanced Raman spectroscopy (SERS).https://www.mdpi.com/1996-1944/15/21/7721silver nanoparticlessurface-enhanced Raman scatteringlow-energy Ar<sup>+</sup> irradiationsurface diffusionresputteringlinear spectroscopy
spellingShingle Oleg Streletskiy
Ilya Zavidovskiy
Dmitry Yakubovsky
Natalia Doroshina
Alexander Syuy
Yury Lebedinskij
Andrey Markeev
Aleksey Arsenin
Valentyn Volkov
Sergey Novikov
Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation
Materials
silver nanoparticles
surface-enhanced Raman scattering
low-energy Ar<sup>+</sup> irradiation
surface diffusion
resputtering
linear spectroscopy
title Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation
title_full Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation
title_fullStr Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation
title_full_unstemmed Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation
title_short Tailoring of the Distribution of SERS-Active Silver Nanoparticles by Post-Deposition Low-Energy Ion Beam Irradiation
title_sort tailoring of the distribution of sers active silver nanoparticles by post deposition low energy ion beam irradiation
topic silver nanoparticles
surface-enhanced Raman scattering
low-energy Ar<sup>+</sup> irradiation
surface diffusion
resputtering
linear spectroscopy
url https://www.mdpi.com/1996-1944/15/21/7721
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