Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
<span style="font-size: medium;"><span style="font-family: Calibri;">In this study, polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide...
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Reaserch Institute of Petroleum Industry
2016-10-01
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Series: | Journal of Petroleum Science and Technology |
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Online Access: | https://jpst.ripi.ir/article_659_fae2e9ad67b2ff5a946b8af572ca9171.pdf |
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author | Maryam Tavakolmoghadam Fatemeh Rekabdar Mahmoud Hemmati Toraj Mohammadi |
author_facet | Maryam Tavakolmoghadam Fatemeh Rekabdar Mahmoud Hemmati Toraj Mohammadi |
author_sort | Maryam Tavakolmoghadam |
collection | DOAJ |
description | <span style="font-size: medium;"><span style="font-family: Calibri;">In this study, polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide (DMAc), which had different affinities with the nonsolvent (water). Properties of the prepared membranes were characterized using scanning electron microscope (SEM) and contact angle and membrane porosity measurements. The prepared membranes were further investigated in terms of pure water flux and BSA rejection in cross flow filtration experiments. The results showed that by using a mixture of DMAc and TEP as solvent and changing the mixed solvent composition, membranes with different morphologies from sponge-like to macrovoid containing were obtained. </span></span><br /><span style="font-family: Calibri;"><span style="font-size: medium;">Maximum flux of the prepared membranes with different solvent mixing ratios was obtained for the one with 60%wt TEP in the casting solution of PVDF/TEP-DMAc/ PEG which equals to 76.8 lm<sup>-2</sup></span><span style="font-size: medium;">h</span><sup><span style="font-size: medium;">-1</span></sup><span style="font-size: medium;">. The effect of addition of </span><span style="font-size: medium;">polyethylene glycol with different molecular weight on morphology and performance of the membranes has also been discussed. </span></span> |
first_indexed | 2024-12-19T09:04:06Z |
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id | doaj.art-75d7f10b33c6409d93da7a3bed295e58 |
institution | Directory Open Access Journal |
issn | 2251-659X 2645-3312 |
language | English |
last_indexed | 2024-12-19T09:04:06Z |
publishDate | 2016-10-01 |
publisher | Reaserch Institute of Petroleum Industry |
record_format | Article |
series | Journal of Petroleum Science and Technology |
spelling | doaj.art-75d7f10b33c6409d93da7a3bed295e582022-12-21T20:28:23ZengReaserch Institute of Petroleum IndustryJournal of Petroleum Science and Technology2251-659X2645-33122016-10-0162112110.22078/jpst.2016.659659Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular WeightMaryam Tavakolmoghadam0Fatemeh Rekabdar1Mahmoud Hemmati2Toraj Mohammadi3Research Institute of Petroleum Industry and Iran university of science and technologyRIPIRIPIIran university of sicence and technology<span style="font-size: medium;"><span style="font-family: Calibri;">In this study, polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide (DMAc), which had different affinities with the nonsolvent (water). Properties of the prepared membranes were characterized using scanning electron microscope (SEM) and contact angle and membrane porosity measurements. The prepared membranes were further investigated in terms of pure water flux and BSA rejection in cross flow filtration experiments. The results showed that by using a mixture of DMAc and TEP as solvent and changing the mixed solvent composition, membranes with different morphologies from sponge-like to macrovoid containing were obtained. </span></span><br /><span style="font-family: Calibri;"><span style="font-size: medium;">Maximum flux of the prepared membranes with different solvent mixing ratios was obtained for the one with 60%wt TEP in the casting solution of PVDF/TEP-DMAc/ PEG which equals to 76.8 lm<sup>-2</sup></span><span style="font-size: medium;">h</span><sup><span style="font-size: medium;">-1</span></sup><span style="font-size: medium;">. The effect of addition of </span><span style="font-size: medium;">polyethylene glycol with different molecular weight on morphology and performance of the membranes has also been discussed. </span></span>https://jpst.ripi.ir/article_659_fae2e9ad67b2ff5a946b8af572ca9171.pdfpolyvinylidene fluoridemixed solventpoly (ethylene) glycolphase inversion |
spellingShingle | Maryam Tavakolmoghadam Fatemeh Rekabdar Mahmoud Hemmati Toraj Mohammadi Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight Journal of Petroleum Science and Technology polyvinylidene fluoride mixed solvent poly (ethylene) glycol phase inversion |
title | Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight |
title_full | Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight |
title_fullStr | Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight |
title_full_unstemmed | Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight |
title_short | Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight |
title_sort | poly vinylidene fluride membrane preparation and characterization effects of mixed solvents and peg molecular weight |
topic | polyvinylidene fluoride mixed solvent poly (ethylene) glycol phase inversion |
url | https://jpst.ripi.ir/article_659_fae2e9ad67b2ff5a946b8af572ca9171.pdf |
work_keys_str_mv | AT maryamtavakolmoghadam polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight AT fatemehrekabdar polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight AT mahmoudhemmati polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight AT torajmohammadi polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight |