Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight

<span style="font-size: medium;"><span style="font-family: Calibri;">In this study, polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide...

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Main Authors: Maryam Tavakolmoghadam, Fatemeh Rekabdar, Mahmoud Hemmati, Toraj Mohammadi
Format: Article
Language:English
Published: Reaserch Institute of Petroleum Industry 2016-10-01
Series:Journal of Petroleum Science and Technology
Subjects:
Online Access:https://jpst.ripi.ir/article_659_fae2e9ad67b2ff5a946b8af572ca9171.pdf
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author Maryam Tavakolmoghadam
Fatemeh Rekabdar
Mahmoud Hemmati
Toraj Mohammadi
author_facet Maryam Tavakolmoghadam
Fatemeh Rekabdar
Mahmoud Hemmati
Toraj Mohammadi
author_sort Maryam Tavakolmoghadam
collection DOAJ
description <span style="font-size: medium;"><span style="font-family: Calibri;">In this study, polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide (DMAc), which had different affinities with the nonsolvent (water). Properties of the prepared membranes were characterized using scanning electron microscope (SEM) and contact angle and membrane porosity measurements. The prepared membranes were further investigated in terms of pure water flux and BSA rejection in cross flow filtration experiments. The results showed that by using a mixture of DMAc and TEP as solvent and changing the mixed solvent composition, membranes with different morphologies from sponge-like to macrovoid containing were obtained. </span></span><br /><span style="font-family: Calibri;"><span style="font-size: medium;">Maximum flux of the prepared membranes with different solvent mixing ratios was obtained for the one with 60%wt TEP in the casting solution of PVDF/TEP-DMAc/ PEG which equals to 76.8 lm<sup>-2</sup></span><span style="font-size: medium;">h</span><sup><span style="font-size: medium;">-1</span></sup><span style="font-size: medium;">. The effect of addition of </span><span style="font-size: medium;">polyethylene glycol with different molecular weight on morphology and performance of the membranes has also been discussed. </span></span>
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spelling doaj.art-75d7f10b33c6409d93da7a3bed295e582022-12-21T20:28:23ZengReaserch Institute of Petroleum IndustryJournal of Petroleum Science and Technology2251-659X2645-33122016-10-0162112110.22078/jpst.2016.659659Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular WeightMaryam Tavakolmoghadam0Fatemeh Rekabdar1Mahmoud Hemmati2Toraj Mohammadi3Research Institute of Petroleum Industry and Iran university of science and technologyRIPIRIPIIran university of sicence and technology<span style="font-size: medium;"><span style="font-family: Calibri;">In this study, polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide (DMAc), which had different affinities with the nonsolvent (water). Properties of the prepared membranes were characterized using scanning electron microscope (SEM) and contact angle and membrane porosity measurements. The prepared membranes were further investigated in terms of pure water flux and BSA rejection in cross flow filtration experiments. The results showed that by using a mixture of DMAc and TEP as solvent and changing the mixed solvent composition, membranes with different morphologies from sponge-like to macrovoid containing were obtained. </span></span><br /><span style="font-family: Calibri;"><span style="font-size: medium;">Maximum flux of the prepared membranes with different solvent mixing ratios was obtained for the one with 60%wt TEP in the casting solution of PVDF/TEP-DMAc/ PEG which equals to 76.8 lm<sup>-2</sup></span><span style="font-size: medium;">h</span><sup><span style="font-size: medium;">-1</span></sup><span style="font-size: medium;">. The effect of addition of </span><span style="font-size: medium;">polyethylene glycol with different molecular weight on morphology and performance of the membranes has also been discussed. </span></span>https://jpst.ripi.ir/article_659_fae2e9ad67b2ff5a946b8af572ca9171.pdfpolyvinylidene fluoridemixed solventpoly (ethylene) glycolphase inversion
spellingShingle Maryam Tavakolmoghadam
Fatemeh Rekabdar
Mahmoud Hemmati
Toraj Mohammadi
Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
Journal of Petroleum Science and Technology
polyvinylidene fluoride
mixed solvent
poly (ethylene) glycol
phase inversion
title Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
title_full Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
title_fullStr Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
title_full_unstemmed Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
title_short Poly (Vinylidene Fluride) Membrane Preparation and Characterization: Effects of Mixed Solvents and PEG Molecular Weight
title_sort poly vinylidene fluride membrane preparation and characterization effects of mixed solvents and peg molecular weight
topic polyvinylidene fluoride
mixed solvent
poly (ethylene) glycol
phase inversion
url https://jpst.ripi.ir/article_659_fae2e9ad67b2ff5a946b8af572ca9171.pdf
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AT fatemehrekabdar polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight
AT mahmoudhemmati polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight
AT torajmohammadi polyvinylidenefluridemembranepreparationandcharacterizationeffectsofmixedsolventsandpegmolecularweight