Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays
This study presents the use of the modified coffee husk and coffee lignin as sorbents in the heavy metal ions sorption of Pb(II), Cd(II), Cr(III), and Cu(II) in an aqueous solution. The modification of sorbents was carried out by the impregnation method, using silver nitrate (AgNO<sub>3</su...
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MDPI AG
2022-06-01
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author | Daniel Fernando Guevara-Bernal Marlon Yesid Cáceres Ortíz Jorge Andrés Gutiérrez Cifuentes Julio Bastos-Arrieta Cristina Palet Angélica María Candela |
author_facet | Daniel Fernando Guevara-Bernal Marlon Yesid Cáceres Ortíz Jorge Andrés Gutiérrez Cifuentes Julio Bastos-Arrieta Cristina Palet Angélica María Candela |
author_sort | Daniel Fernando Guevara-Bernal |
collection | DOAJ |
description | This study presents the use of the modified coffee husk and coffee lignin as sorbents in the heavy metal ions sorption of Pb(II), Cd(II), Cr(III), and Cu(II) in an aqueous solution. The modification of sorbents was carried out by the impregnation method, using silver nitrate (AgNO<sub>3</sub>) and sodium borohydride (NaBH<sub>4</sub>) as a nanoparticles’ (NPs) precursor, and reducing agent, respectively. The obtained nanocomposite material was morphologically characterized by electron microscopy. In addition, an evaluation of metal ions’ sorption, pseudo-first-order, and pseudo-second-order kinetics modeling was performed. Finally, antifungal activity was evaluated on different <i>Candida</i> species. Coffee and lignin modified with AgNPs increased the extraction capacity with the highest sorption for Pb ions with 2.56 mg/g and 1.44 mg/g, respectively. |
first_indexed | 2024-03-10T00:44:09Z |
format | Article |
id | doaj.art-75dec6f1fa174eac80200395db06b48a |
institution | Directory Open Access Journal |
issn | 2073-4441 |
language | English |
last_indexed | 2024-03-10T00:44:09Z |
publishDate | 2022-06-01 |
publisher | MDPI AG |
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series | Water |
spelling | doaj.art-75dec6f1fa174eac80200395db06b48a2023-11-23T15:03:02ZengMDPI AGWater2073-44412022-06-011411179610.3390/w14111796Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal AssaysDaniel Fernando Guevara-Bernal0Marlon Yesid Cáceres Ortíz1Jorge Andrés Gutiérrez Cifuentes2Julio Bastos-Arrieta3Cristina Palet4Angélica María Candela5Grupo de Investigación en Nuevos Materiales y Energías Alternativas, Facultad de Química Ambiental, Universidad Santo Tomás, Floridablanca 681003, ColombiaGrupo de Investigación en Bioquímica y Microbiología, Escuela de Química, Facultad de Ciencias, Universidad Industrial de Santander, Bucaramanga 680002, ColombiaFacultad de Ciencias de la Salud, Universidad del Quindío, Armenia 630004, ColombiaGrup d’Electroanàlisi, Department of Chemical Engineering and Analytical Chemistry, Universitat de Barcelona, Carrer Martí i Franqués 1-11, 08028 Barcelona, SpainGrup de Tècniques de Separació en Química, Unitat Química Analítica, Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193 Bellaterra, SpainGrupo de Investigación en Nuevos Materiales y Energías Alternativas, Facultad de Química Ambiental, Universidad Santo Tomás, Floridablanca 681003, ColombiaThis study presents the use of the modified coffee husk and coffee lignin as sorbents in the heavy metal ions sorption of Pb(II), Cd(II), Cr(III), and Cu(II) in an aqueous solution. The modification of sorbents was carried out by the impregnation method, using silver nitrate (AgNO<sub>3</sub>) and sodium borohydride (NaBH<sub>4</sub>) as a nanoparticles’ (NPs) precursor, and reducing agent, respectively. The obtained nanocomposite material was morphologically characterized by electron microscopy. In addition, an evaluation of metal ions’ sorption, pseudo-first-order, and pseudo-second-order kinetics modeling was performed. Finally, antifungal activity was evaluated on different <i>Candida</i> species. Coffee and lignin modified with AgNPs increased the extraction capacity with the highest sorption for Pb ions with 2.56 mg/g and 1.44 mg/g, respectively.https://www.mdpi.com/2073-4441/14/11/1796coffee huskligninheavy metalssilver nanoparticlessorptionantifungal activity |
spellingShingle | Daniel Fernando Guevara-Bernal Marlon Yesid Cáceres Ortíz Jorge Andrés Gutiérrez Cifuentes Julio Bastos-Arrieta Cristina Palet Angélica María Candela Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays Water coffee husk lignin heavy metals silver nanoparticles sorption antifungal activity |
title | Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays |
title_full | Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays |
title_fullStr | Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays |
title_full_unstemmed | Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays |
title_short | Coffee Husk and Lignin Revalorization: Modification with Ag Nanoparticles for Heavy Metals Removal and Antifungal Assays |
title_sort | coffee husk and lignin revalorization modification with ag nanoparticles for heavy metals removal and antifungal assays |
topic | coffee husk lignin heavy metals silver nanoparticles sorption antifungal activity |
url | https://www.mdpi.com/2073-4441/14/11/1796 |
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