Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis
Phosphonyl and carboxyl groups are valuable functional groups, however their simultaneous incorporation via catalytic difunctionalization of alkenes has not been realized yet. Here the authors report the phosphonocarboxylation of alkenes with CO2 via visible-light photoredox catalysis.
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2019-08-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-11528-8 |
| _version_ | 1819036109812793344 |
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| author | Qiang Fu Zhi-Yu Bo Jian-Heng Ye Tao Ju He Huang Li-Li Liao Da-Gang Yu |
| author_facet | Qiang Fu Zhi-Yu Bo Jian-Heng Ye Tao Ju He Huang Li-Li Liao Da-Gang Yu |
| author_sort | Qiang Fu |
| collection | DOAJ |
| description | Phosphonyl and carboxyl groups are valuable functional groups, however their simultaneous incorporation via catalytic difunctionalization of alkenes has not been realized yet. Here the authors report the phosphonocarboxylation of alkenes with CO2 via visible-light photoredox catalysis. |
| first_indexed | 2024-12-21T08:00:18Z |
| format | Article |
| id | doaj.art-75e6e53c912b4d1dac7a1c83c2c6ee58 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-21T08:00:18Z |
| publishDate | 2019-08-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-75e6e53c912b4d1dac7a1c83c2c6ee582022-12-21T19:10:55ZengNature PortfolioNature Communications2041-17232019-08-011011910.1038/s41467-019-11528-8Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysisQiang Fu0Zhi-Yu Bo1Jian-Heng Ye2Tao Ju3He Huang4Li-Li Liao5Da-Gang Yu6Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan UniversityPhosphonyl and carboxyl groups are valuable functional groups, however their simultaneous incorporation via catalytic difunctionalization of alkenes has not been realized yet. Here the authors report the phosphonocarboxylation of alkenes with CO2 via visible-light photoredox catalysis.https://doi.org/10.1038/s41467-019-11528-8 |
| spellingShingle | Qiang Fu Zhi-Yu Bo Jian-Heng Ye Tao Ju He Huang Li-Li Liao Da-Gang Yu Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis Nature Communications |
| title | Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis |
| title_full | Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis |
| title_fullStr | Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis |
| title_full_unstemmed | Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis |
| title_short | Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis |
| title_sort | transition metal free phosphonocarboxylation of alkenes with carbon dioxide via visible light photoredox catalysis |
| url | https://doi.org/10.1038/s41467-019-11528-8 |
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