Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc
The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate ZnII complex molecules. In each molecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramid...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811025669 |
| _version_ | 1828129744686678016 |
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| author | Nura Suleiman Gwaram Hamid Khaledi Hapipah Mohd Ali |
| author_facet | Nura Suleiman Gwaram Hamid Khaledi Hapipah Mohd Ali |
| author_sort | Nura Suleiman Gwaram |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate ZnII complex molecules. In each molecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C—H...Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by π–π interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid–centroid distances = 3.6255 (10) and 3.7073 (10) Å]. The crystal lattice contains void spaces with a size of 52 Å3. |
| first_indexed | 2024-04-11T16:24:36Z |
| format | Article |
| id | doaj.art-75f12fa0ea6e445c9ff1024f3e62f0fb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:24:36Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-75f12fa0ea6e445c9ff1024f3e62f0fb2022-12-22T04:14:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1027m102710.1107/S1600536811025669Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zincNura Suleiman GwaramHamid KhalediHapipah Mohd AliThe asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate ZnII complex molecules. In each molecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C—H...Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by π–π interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid–centroid distances = 3.6255 (10) and 3.7073 (10) Å]. The crystal lattice contains void spaces with a size of 52 Å3.http://scripts.iucr.org/cgi-bin/paper?S1600536811025669 |
| spellingShingle | Nura Suleiman Gwaram Hamid Khaledi Hapipah Mohd Ali Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc Acta Crystallographica Section E |
| title | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc |
| title_full | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc |
| title_fullStr | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc |
| title_full_unstemmed | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc |
| title_short | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ3N,N′,N′′}zinc |
| title_sort | dichlorido n n dimethyl n amp 8242 1 2 pyridyl ethylidene ethane 1 2 diamine amp 954 3n n amp 8242 n amp 8242 amp 8242 zinc |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811025669 |
| work_keys_str_mv | AT nurasuleimangwaram dichloridonndimethylnamp824212pyridylethylideneethane12diamineamp9543nnamp8242namp8242amp8242zinc AT hamidkhaledi dichloridonndimethylnamp824212pyridylethylideneethane12diamineamp9543nnamp8242namp8242amp8242zinc AT hapipahmohdali dichloridonndimethylnamp824212pyridylethylideneethane12diamineamp9543nnamp8242namp8242amp8242zinc |