Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate

The asymmetric unit of the title compound, [Cu2Tb(C7H3NO4)3(C12H8N2)4]NO3·4H2O, consists of one-half of the C2-symmetric trinuclear coordination cation, one-half of the C2-symmetric nitrate anion and two water molecules. In the coordination cation, the CuII atom is coordinated by four N...

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Main Author: Wei Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2012-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812031686
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author Wei Zhang
author_facet Wei Zhang
author_sort Wei Zhang
collection DOAJ
description The asymmetric unit of the title compound, [Cu2Tb(C7H3NO4)3(C12H8N2)4]NO3·4H2O, consists of one-half of the C2-symmetric trinuclear coordination cation, one-half of the C2-symmetric nitrate anion and two water molecules. In the coordination cation, the CuII atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from a bridging–chelating carboxylate group of the pyridine-2,6-dicarboxylate anion, completing a distorted N4O2 octahedral coordination environment. The TbIII atom, located on a twofold rotation axis, is nine-coordinated by three tridentate pyridine-2,6-dicarboxylate anions forming an N3O6 donor set. The intramolecular Cu...Tb distance of 5.0592 (11) Å indicates weak interactions between the CuII and TbIII atoms. The coordination cations, nitrate anions and water molecules are connected via O—H...O hydrogen bonds into layers parallel to the (001) plane. Moreover, there are extensive π–π stacking interactions [centroid–centroid distances = 4.332 (7) and 3.878 (5) Å] between the phenanthroline ligands and between phenanthroline and pyridine-2,6-dicarboxylate ligands.
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spelling doaj.art-7607aef59eb14558934fd49dfa95b0a72022-12-21T23:50:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-08-01688m1084m108510.1107/S1600536812031686Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrateWei ZhangThe asymmetric unit of the title compound, [Cu2Tb(C7H3NO4)3(C12H8N2)4]NO3·4H2O, consists of one-half of the C2-symmetric trinuclear coordination cation, one-half of the C2-symmetric nitrate anion and two water molecules. In the coordination cation, the CuII atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from a bridging–chelating carboxylate group of the pyridine-2,6-dicarboxylate anion, completing a distorted N4O2 octahedral coordination environment. The TbIII atom, located on a twofold rotation axis, is nine-coordinated by three tridentate pyridine-2,6-dicarboxylate anions forming an N3O6 donor set. The intramolecular Cu...Tb distance of 5.0592 (11) Å indicates weak interactions between the CuII and TbIII atoms. The coordination cations, nitrate anions and water molecules are connected via O—H...O hydrogen bonds into layers parallel to the (001) plane. Moreover, there are extensive π–π stacking interactions [centroid–centroid distances = 4.332 (7) and 3.878 (5) Å] between the phenanthroline ligands and between phenanthroline and pyridine-2,6-dicarboxylate ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536812031686
spellingShingle Wei Zhang
Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate
Acta Crystallographica Section E
title Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate
title_full Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate
title_fullStr Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate
title_full_unstemmed Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate
title_short Tetrakis(1,10-phenanthroline)bis(μ-pyridine-2,6-dicarboxylato)(pyridine-2,6-dicarboxylato)dicopper(II)terbium(III) nitrate tetrahydrate
title_sort tetrakis 1 10 phenanthroline bis amp 956 pyridine 2 6 dicarboxylato pyridine 2 6 dicarboxylato dicopper ii terbium iii nitrate tetrahydrate
url http://scripts.iucr.org/cgi-bin/paper?S1600536812031686
work_keys_str_mv AT weizhang tetrakis110phenanthrolinebisamp956pyridine26dicarboxylatopyridine26dicarboxylatodicopperiiterbiumiiinitratetetrahydrate