GC-MS Studies on Nitric Oxide Autoxidation and <i>S</i>-Nitrosothiol Hydrolysis to Nitrite in pH-Neutral Aqueous Buffers: Definite Results Using <sup>15</sup>N and <sup>18</sup>O Isotopes

GC-MS Studies on Nitric Oxide Autoxidation and <i>S</i>-Nitrosothiol Hydrolysis to Nitrite in pH-Neutral Aqueous Buffers: Definite Results Using <sup>15</sup>N and <sup>18</sup>O Isotopes

Nitrite (O=N-O<sup>−</sup>, NO<sub>2</sub><sup>−</sup>) and nitrate (O=N(O)-O<sup>−</sup>, NO<sub>3</sub><sup>−</sup>) are ubiquitous in nature. In aerated aqueous solutions, nitrite is considered the major autoxidation product...

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Bibliographic Details
Main Author: Dimitrios Tsikas
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
autoxidation
derivatization
GC-MS
nitric oxide
pentafluorobenzyl bromide
stable isotopes
Online Access:https://www.mdpi.com/1420-3049/28/11/4281

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