Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method

Based on a “filter press backwash–chemical precipitation–gaseous membrane absorption” process, treatment of harmless cyanide tailings was conducted using cyanide tailings from a gold smelting enterprises (Yunnan Province, China) as the research object. The effects of air-drying time, backwash water...

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Main Authors: Jingmin Yan, Yanhua Wang, Yubo Tu, Peiwei Han, Xiang Liu, Shufeng Ye
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/5/2091
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author Jingmin Yan
Yanhua Wang
Yubo Tu
Peiwei Han
Xiang Liu
Shufeng Ye
author_facet Jingmin Yan
Yanhua Wang
Yubo Tu
Peiwei Han
Xiang Liu
Shufeng Ye
author_sort Jingmin Yan
collection DOAJ
description Based on a “filter press backwash–chemical precipitation–gaseous membrane absorption” process, treatment of harmless cyanide tailings was conducted using cyanide tailings from a gold smelting enterprises (Yunnan Province, China) as the research object. The effects of air-drying time, backwash water parameters, initial pH of acidification, NaHS dosage, cyanide-containing water flow rate, and gaseous membrane stages on the process were investigated. Chemical composition, X-ray diffraction, and X-ray photoelectron spectroscopy analyses of the copper products were carried out. Results showed that the copper content in the copper product was 54.56%, and the chemical composition was mainly CuSCN, CuS, Cu<sub>2</sub>S, and CaSO<sub>4</sub>. Five cycles of experiments were carried out under optimal conditions; the results showed that the process can make the treated cyanide tailings meet the requirements of the technical specification for pollution control of cyanide leaching residue in the gold industry (TSPC) standard for storage in a tailings pond and a have certain stability. The average recovery rate of copper and total cyanide in elution water was 97.8% and 99.89%, respectively, and the average removal rate of thiocyanate was 94.09%.
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spelling doaj.art-7641c4cfd7594c51b8d30a177bde56372023-12-11T18:37:06ZengMDPI AGApplied Sciences2076-34172021-02-01115209110.3390/app11052091Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” MethodJingmin Yan0Yanhua Wang1Yubo Tu2Peiwei Han3Xiang Liu4Shufeng Ye5State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaState Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaState Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, 100041 Beijing, ChinaState Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaState Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaState Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaBased on a “filter press backwash–chemical precipitation–gaseous membrane absorption” process, treatment of harmless cyanide tailings was conducted using cyanide tailings from a gold smelting enterprises (Yunnan Province, China) as the research object. The effects of air-drying time, backwash water parameters, initial pH of acidification, NaHS dosage, cyanide-containing water flow rate, and gaseous membrane stages on the process were investigated. Chemical composition, X-ray diffraction, and X-ray photoelectron spectroscopy analyses of the copper products were carried out. Results showed that the copper content in the copper product was 54.56%, and the chemical composition was mainly CuSCN, CuS, Cu<sub>2</sub>S, and CaSO<sub>4</sub>. Five cycles of experiments were carried out under optimal conditions; the results showed that the process can make the treated cyanide tailings meet the requirements of the technical specification for pollution control of cyanide leaching residue in the gold industry (TSPC) standard for storage in a tailings pond and a have certain stability. The average recovery rate of copper and total cyanide in elution water was 97.8% and 99.89%, respectively, and the average removal rate of thiocyanate was 94.09%.https://www.mdpi.com/2076-3417/11/5/2091cyanide tailingsharmlessgaseous membranewastewater
spellingShingle Jingmin Yan
Yanhua Wang
Yubo Tu
Peiwei Han
Xiang Liu
Shufeng Ye
Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method
Applied Sciences
cyanide tailings
harmless
gaseous membrane
wastewater
title Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method
title_full Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method
title_fullStr Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method
title_full_unstemmed Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method
title_short Green Treatment of Cyanide Tailings Using a “Filter Press BackWash–Chemical Precipitation–Gaseous Membrane Absorption” Method
title_sort green treatment of cyanide tailings using a filter press backwash chemical precipitation gaseous membrane absorption method
topic cyanide tailings
harmless
gaseous membrane
wastewater
url https://www.mdpi.com/2076-3417/11/5/2091
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