Effects of molecular diffusion length on area-selective growth of organic patterns

Oganic devices have gained much progress in the past decades, as a promising candidate for flexible/wearable electronics. However, the realization of organic microelectronic systems for wide applications is still difficult, due to the incompatibility of organic semiconductors (OSCs) with the convent...

Full description

Bibliographic Details
Main Authors: Yue Jiang, Yichen Cai, Jianping Li, Naibo Chen, Laigui Hu, Wenchong Wang, Qing-Miao Nie, Bo Yan
Format: Article
Language:English
Published: IOP Publishing 2022-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ac5954
_version_ 1797746607061467136
author Yue Jiang
Yichen Cai
Jianping Li
Naibo Chen
Laigui Hu
Wenchong Wang
Qing-Miao Nie
Bo Yan
author_facet Yue Jiang
Yichen Cai
Jianping Li
Naibo Chen
Laigui Hu
Wenchong Wang
Qing-Miao Nie
Bo Yan
author_sort Yue Jiang
collection DOAJ
description Oganic devices have gained much progress in the past decades, as a promising candidate for flexible/wearable electronics. However, the realization of organic microelectronic systems for wide applications is still difficult, due to the incompatibility of organic semiconductors (OSCs) with the conventional top-down lithography techniques for inorganics. To solve this challenge, bottom-up lithography-compatible methods have been developed for organic device arrays, i.e., template-directed growth or area-selective growth (ASG). Unfortunately, the physics on the dynamic process of the ASG method for molecular semiconductors is still not well understood. In order to explore this issue, the growth of particles on prepatterned surfaces under different diffusion lengths ( L _d ) was simulated in a microscopic point of view by using kinetic Monte Carlo method. Simulation results show that ASG of the particles is strongly related to the L _d of the particles, periodicity and size of prepatterned surfaces. It is notable that such simulated results were found to fit well with those of our experiments, which can be favorable for improving the ASG method for patterning functional molecules.
first_indexed 2024-03-12T15:39:16Z
format Article
id doaj.art-764200410c3f4328a7f9ba8bbe8bd9f2
institution Directory Open Access Journal
issn 2053-1591
language English
last_indexed 2024-03-12T15:39:16Z
publishDate 2022-01-01
publisher IOP Publishing
record_format Article
series Materials Research Express
spelling doaj.art-764200410c3f4328a7f9ba8bbe8bd9f22023-08-09T16:02:49ZengIOP PublishingMaterials Research Express2053-15912022-01-019303510110.1088/2053-1591/ac5954Effects of molecular diffusion length on area-selective growth of organic patternsYue Jiang0Yichen Cai1Jianping Li2Naibo Chen3Laigui Hu4Wenchong Wang5Qing-Miao Nie6https://orcid.org/0000-0001-7146-0555Bo Yan7https://orcid.org/0000-0002-7885-8109Department of Applied Physics, Zhejiang University of Technology , 288, Liuhe Road,Hangzhou, 310023, People’s Republic of ChinaSchool of Information Science and Technology, Fudan University , Shanghai 200433, People’s Republic of ChinaSchool of Information Science and Technology, Fudan University , Shanghai 200433, People’s Republic of ChinaDepartment of Applied Physics, Zhejiang University of Technology , 288, Liuhe Road,Hangzhou, 310023, People’s Republic of ChinaSchool of Information Science and Technology, Fudan University , Shanghai 200433, People’s Republic of ChinaPhysikalisches Institut and Center for Nanotechnology, Universität3 Physikalisches Institut and Center for Nanotechnology , Universität Münster, Wilhelm-Klemm-Straße 10, 48149 Münster, GermanyDepartment of Applied Physics, Zhejiang University of Technology , 288, Liuhe Road,Hangzhou, 310023, People’s Republic of ChinaDepartment of Applied Physics, Zhejiang University of Technology , 288, Liuhe Road,Hangzhou, 310023, People’s Republic of ChinaOganic devices have gained much progress in the past decades, as a promising candidate for flexible/wearable electronics. However, the realization of organic microelectronic systems for wide applications is still difficult, due to the incompatibility of organic semiconductors (OSCs) with the conventional top-down lithography techniques for inorganics. To solve this challenge, bottom-up lithography-compatible methods have been developed for organic device arrays, i.e., template-directed growth or area-selective growth (ASG). Unfortunately, the physics on the dynamic process of the ASG method for molecular semiconductors is still not well understood. In order to explore this issue, the growth of particles on prepatterned surfaces under different diffusion lengths ( L _d ) was simulated in a microscopic point of view by using kinetic Monte Carlo method. Simulation results show that ASG of the particles is strongly related to the L _d of the particles, periodicity and size of prepatterned surfaces. It is notable that such simulated results were found to fit well with those of our experiments, which can be favorable for improving the ASG method for patterning functional molecules.https://doi.org/10.1088/2053-1591/ac5954kinetic Monte Carloarea-selective growthdiffusion length
spellingShingle Yue Jiang
Yichen Cai
Jianping Li
Naibo Chen
Laigui Hu
Wenchong Wang
Qing-Miao Nie
Bo Yan
Effects of molecular diffusion length on area-selective growth of organic patterns
Materials Research Express
kinetic Monte Carlo
area-selective growth
diffusion length
title Effects of molecular diffusion length on area-selective growth of organic patterns
title_full Effects of molecular diffusion length on area-selective growth of organic patterns
title_fullStr Effects of molecular diffusion length on area-selective growth of organic patterns
title_full_unstemmed Effects of molecular diffusion length on area-selective growth of organic patterns
title_short Effects of molecular diffusion length on area-selective growth of organic patterns
title_sort effects of molecular diffusion length on area selective growth of organic patterns
topic kinetic Monte Carlo
area-selective growth
diffusion length
url https://doi.org/10.1088/2053-1591/ac5954
work_keys_str_mv AT yuejiang effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT yichencai effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT jianpingli effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT naibochen effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT laiguihu effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT wenchongwang effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT qingmiaonie effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns
AT boyan effectsofmoleculardiffusionlengthonareaselectivegrowthoforganicpatterns