Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium
The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812016558 |
| _version_ | 1828854196292550656 |
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| author | Leandro Bresolin Vanessa Carratu Gervini Adriano Bof de Oliveira Alexandra de Souza Fonseca Aline Locatelli |
| author_facet | Leandro Bresolin Vanessa Carratu Gervini Adriano Bof de Oliveira Alexandra de Souza Fonseca Aline Locatelli |
| author_sort | Leandro Bresolin |
| collection | DOAJ |
| description | The reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N—H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1]. |
| first_indexed | 2024-12-13T00:28:03Z |
| format | Article |
| id | doaj.art-765f3fa655e641e2bc0778c19f32257e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:28:03Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-765f3fa655e641e2bc0778c19f32257e2022-12-22T00:05:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m635m63610.1107/S1600536812016558Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmiumLeandro BresolinVanessa Carratu GerviniAdriano Bof de OliveiraAlexandra de Souza FonsecaAline LocatelliThe reaction of cadmium acetate dihydrate with 2-acetylpyridine (4-phenylthiosemicarbazone) yielded the title compound, [Cd(C14H13N4S)2]. The CdII atom is six-coordinated in a distorted octahedral environment by two deprotonated thiosemicarbazone ligands acting in a tridentate chelating mode through two N and one S atoms, forming metalla-rings. In the crystal, molecules are connected through inversion centers via pairs of N—H...S interactions, building a one-dimensional hydrogen-bonded polymer along [0-1-1].http://scripts.iucr.org/cgi-bin/paper?S1600536812016558 |
| spellingShingle | Leandro Bresolin Vanessa Carratu Gervini Adriano Bof de Oliveira Alexandra de Souza Fonseca Aline Locatelli Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium Acta Crystallographica Section E |
| title | Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium |
| title_full | Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium |
| title_fullStr | Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium |
| title_full_unstemmed | Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium |
| title_short | Bis{4-phenyl-1-[1-(pyridin-2-yl-κN)ethylidene]thiosemicarbazidato-κ2N1,S}cadmium |
| title_sort | bis 4 phenyl 1 1 pyridin 2 yl amp 954 n ethylidene thiosemicarbazidato amp 954 2n1 s cadmium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812016558 |
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