Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate
The asymmetric unit of the title compound, [Ni(HCO2)2(C14H12N2)(H2O)]·H2O, contains a mononuclear complex molecule hydrogen bonded to a lattice water molecule. The NiII atom exhibits a distorted octahedral coordination geometry formed by the N atoms from a 2,9-dimethyl-1,10-phenanthroli...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811030558 |
| _version_ | 1819110674451660800 |
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| author | Ping Xia Jian-Li Lin Sheng-Liang Ni |
| author_facet | Ping Xia Jian-Li Lin Sheng-Liang Ni |
| author_sort | Ping Xia |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Ni(HCO2)2(C14H12N2)(H2O)]·H2O, contains a mononuclear complex molecule hydrogen bonded to a lattice water molecule. The NiII atom exhibits a distorted octahedral coordination geometry formed by the N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, two O atoms of a chelating formate anion, one aqua O atom and one O atom of a coordinating formate anion. The molecules are assembled into chains extending along [100] through by O—H...O hydrogen bonds. The supramolecular chains are further linked into layers parallel to (011) by weak π–π packing interactions [centroid–centroid separation = 3.768 (2) Å]. The resulting layers are stacked to meet the requirement of close-packing patterns. |
| first_indexed | 2024-12-22T03:45:28Z |
| format | Article |
| id | doaj.art-7663e3ecdbd741b097171becde63dd49 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T03:45:28Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-7663e3ecdbd741b097171becde63dd492022-12-21T18:40:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1181m118110.1107/S1600536811030558Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydratePing XiaJian-Li LinSheng-Liang NiThe asymmetric unit of the title compound, [Ni(HCO2)2(C14H12N2)(H2O)]·H2O, contains a mononuclear complex molecule hydrogen bonded to a lattice water molecule. The NiII atom exhibits a distorted octahedral coordination geometry formed by the N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, two O atoms of a chelating formate anion, one aqua O atom and one O atom of a coordinating formate anion. The molecules are assembled into chains extending along [100] through by O—H...O hydrogen bonds. The supramolecular chains are further linked into layers parallel to (011) by weak π–π packing interactions [centroid–centroid separation = 3.768 (2) Å]. The resulting layers are stacked to meet the requirement of close-packing patterns.http://scripts.iucr.org/cgi-bin/paper?S1600536811030558 |
| spellingShingle | Ping Xia Jian-Li Lin Sheng-Liang Ni Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate Acta Crystallographica Section E |
| title | Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate |
| title_full | Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate |
| title_fullStr | Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate |
| title_full_unstemmed | Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate |
| title_short | Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)diformato-κ2O,O′;κO-nickel(II) monohydrate |
| title_sort | aqua 2 9 dimethyl 1 10 phenanthroline amp 954 2n n amp 8242 diformato amp 954 2o o amp 8242 amp 954 o nickel ii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811030558 |
| work_keys_str_mv | AT pingxia aqua29dimethyl110phenanthrolineamp9542nnamp8242diformatoamp9542ooamp8242amp954onickeliimonohydrate AT jianlilin aqua29dimethyl110phenanthrolineamp9542nnamp8242diformatoamp9542ooamp8242amp954onickeliimonohydrate AT shengliangni aqua29dimethyl110phenanthrolineamp9542nnamp8242diformatoamp9542ooamp8242amp954onickeliimonohydrate |