Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration
Surface modification could increase affinity of PET fibers to polymer matrix by changing the interfacial physical interactions to covalent bonds. In this research, surface modification of a superfine polyethylene terephthalate (PET) fabric was performed by bis(triethoxysilylpropyl)tetrasulfide (TESP...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-09-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535223005609 |
| _version_ | 1797776659778109440 |
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| author | Mohammad Sayyadian Masoud Jamshidi Reza Ghamarpoor Mahmoud Razavizadeh |
| author_facet | Mohammad Sayyadian Masoud Jamshidi Reza Ghamarpoor Mahmoud Razavizadeh |
| author_sort | Mohammad Sayyadian |
| collection | DOAJ |
| description | Surface modification could increase affinity of PET fibers to polymer matrix by changing the interfacial physical interactions to covalent bonds. In this research, surface modification of a superfine polyethylene terephthalate (PET) fabric was performed by bis(triethoxysilylpropyl)tetrasulfide (TESPT). The surface grafting was performed at different silane concentrations (i.e. 1, 5 and 10X). Before silanization, the fabrics were functionalized using photochemical method (i.e. irradiation of UV light in presence of glutaric acid peroxide (GAP)) and also hydrolysis by Sodium hydroxide (NaOH). Due to functionalization, carboxyl and hydroxyl groups were formed on the PET surface that made it ready to condense with hydrolyzed silane molecules. The fabrics were characterized using FTIR, TGA, FE-SEM, XPS analysis for evaluation of grafting performances. XPS analysis confirmed the presence of new peaks of Si and S after surface modification with TESPT. Comparing the results of TESPT-grafted functionalized PETs, it was found that the silane grafting content on PET surface is dependent not only to the silane concentration but also to the functionalization method. Finally, the influences of silane grafting on the functionalized PET fabrics to NBR adhesion were evaluated using H-pull and T-peel tests. The results showed that silane grafted-carboxylated PET fabric illustrated more adhesion to NBR than silane grafted-hydroxylated PET (i.e. 33 and 12% improvement in the pullout strength and T-peel adhesion, respectively). |
| first_indexed | 2024-03-12T22:53:05Z |
| format | Article |
| id | doaj.art-766c815cbd2641dea22d3284a29f91c1 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-03-12T22:53:05Z |
| publishDate | 2023-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-766c815cbd2641dea22d3284a29f91c12023-07-20T04:38:08ZengElsevierArabian Journal of Chemistry1878-53522023-09-01169105098Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentrationMohammad Sayyadian0Masoud Jamshidi1Reza Ghamarpoor2Mahmoud Razavizadeh3Constructional Polymers and Composites Research Lab, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology (IUST), Tehran, IranConstructional Polymers and Composites Research Lab, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology (IUST), Tehran, Iran; Corresponding author.Constructional Polymers and Composites Research Lab, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology (IUST), Tehran, IranDepartment of Polymer Engineering, Faculty of Materials and Manufacturing, Malek Ashtar University of Technology, Tehran, IranSurface modification could increase affinity of PET fibers to polymer matrix by changing the interfacial physical interactions to covalent bonds. In this research, surface modification of a superfine polyethylene terephthalate (PET) fabric was performed by bis(triethoxysilylpropyl)tetrasulfide (TESPT). The surface grafting was performed at different silane concentrations (i.e. 1, 5 and 10X). Before silanization, the fabrics were functionalized using photochemical method (i.e. irradiation of UV light in presence of glutaric acid peroxide (GAP)) and also hydrolysis by Sodium hydroxide (NaOH). Due to functionalization, carboxyl and hydroxyl groups were formed on the PET surface that made it ready to condense with hydrolyzed silane molecules. The fabrics were characterized using FTIR, TGA, FE-SEM, XPS analysis for evaluation of grafting performances. XPS analysis confirmed the presence of new peaks of Si and S after surface modification with TESPT. Comparing the results of TESPT-grafted functionalized PETs, it was found that the silane grafting content on PET surface is dependent not only to the silane concentration but also to the functionalization method. Finally, the influences of silane grafting on the functionalized PET fabrics to NBR adhesion were evaluated using H-pull and T-peel tests. The results showed that silane grafted-carboxylated PET fabric illustrated more adhesion to NBR than silane grafted-hydroxylated PET (i.e. 33 and 12% improvement in the pullout strength and T-peel adhesion, respectively).http://www.sciencedirect.com/science/article/pii/S1878535223005609Surface modificationAdhesionPET FabricNitrile rubber (NBR)TESPT |
| spellingShingle | Mohammad Sayyadian Masoud Jamshidi Reza Ghamarpoor Mahmoud Razavizadeh Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration Arabian Journal of Chemistry Surface modification Adhesion PET Fabric Nitrile rubber (NBR) TESPT |
| title | Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration |
| title_full | Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration |
| title_fullStr | Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration |
| title_full_unstemmed | Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration |
| title_short | Silanization of functionalized PET fabric to improve PET-nitrile rubber (NBR) adhesion; effects of functionalization type and silane concentration |
| title_sort | silanization of functionalized pet fabric to improve pet nitrile rubber nbr adhesion effects of functionalization type and silane concentration |
| topic | Surface modification Adhesion PET Fabric Nitrile rubber (NBR) TESPT |
| url | http://www.sciencedirect.com/science/article/pii/S1878535223005609 |
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