[5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV)
In title compound, [Sn(C6H5)3(C9H6BrN2OS2)], the Sn atom is five-coordinated and the 1,3,4-thiadiazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate SnIV atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a dis...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809012793 |
| _version_ | 1818894037718925312 |
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| author | Lai-jin Tian Zhi-feng Wang Gui-long Zhao |
| author_facet | Lai-jin Tian Zhi-feng Wang Gui-long Zhao |
| author_sort | Lai-jin Tian |
| collection | DOAJ |
| description | In title compound, [Sn(C6H5)3(C9H6BrN2OS2)], the Sn atom is five-coordinated and the 1,3,4-thiadiazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate SnIV atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a distorted cis-trigonal bipyramidal geometry with the S atom and two C atoms occupying the equatorial plane, whereas the N atom and another C atom are in axial positions. In addition, there is a weak intramolecular Sn...N interaction. The crystal structure involves weak intramolecular C—H...N and intermolecular C—H...Br hydrogen bonding. |
| first_indexed | 2024-12-19T18:22:08Z |
| format | Article |
| id | doaj.art-766d3c1b64ec443eb458fa00d1fe7de2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:22:08Z |
| publishDate | 2009-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-766d3c1b64ec443eb458fa00d1fe7de22022-12-21T20:10:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655m528m52810.1107/S1600536809012793[5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV)Lai-jin TianZhi-feng WangGui-long ZhaoIn title compound, [Sn(C6H5)3(C9H6BrN2OS2)], the Sn atom is five-coordinated and the 1,3,4-thiadiazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate SnIV atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a distorted cis-trigonal bipyramidal geometry with the S atom and two C atoms occupying the equatorial plane, whereas the N atom and another C atom are in axial positions. In addition, there is a weak intramolecular Sn...N interaction. The crystal structure involves weak intramolecular C—H...N and intermolecular C—H...Br hydrogen bonding.http://scripts.iucr.org/cgi-bin/paper?S1600536809012793 |
| spellingShingle | Lai-jin Tian Zhi-feng Wang Gui-long Zhao [5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV) Acta Crystallographica Section E |
| title | [5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV) |
| title_full | [5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV) |
| title_fullStr | [5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV) |
| title_full_unstemmed | [5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV) |
| title_short | [5-(4-Bromophenoxymethyl)-1,3,4-thiadiazole-2-thiolato]triphenyltin(IV) |
| title_sort | 5 4 bromophenoxymethyl 1 3 4 thiadiazole 2 thiolato triphenyltin iv |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809012793 |
| work_keys_str_mv | AT laijintian 54bromophenoxymethyl134thiadiazole2thiolatotriphenyltiniv AT zhifengwang 54bromophenoxymethyl134thiadiazole2thiolatotriphenyltiniv AT guilongzhao 54bromophenoxymethyl134thiadiazole2thiolatotriphenyltiniv |