Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings

The main idea of the research is to formulate alkyd based smart coatings with high NIR-reflectance to decrease the cooling load in order to maintain cool comfort in buildings. In addition to the NIR reflectance studies, the physical characteristics of the coating such as glossiness, hiding power, sp...

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Main Authors: V S Benitha, K Jeyasubramanian, V S Prabhin
Format: Article
Language:English
Published: IOP Publishing 2022-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ac6fbd
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author V S Benitha
K Jeyasubramanian
V S Prabhin
author_facet V S Benitha
K Jeyasubramanian
V S Prabhin
author_sort V S Benitha
collection DOAJ
description The main idea of the research is to formulate alkyd based smart coatings with high NIR-reflectance to decrease the cooling load in order to maintain cool comfort in buildings. In addition to the NIR reflectance studies, the physical characteristics of the coating such as glossiness, hiding power, spreading area, volatile organic contents are evaluated. Heat reflective coatings are prepared by ball milling technique utilizing white metal oxide nanoparticles (NPs) titanium oxide (TiO _2 ), zinc oxide (ZnO) and zirconium oxide (ZrO _2 ) as pigments. The x-ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) results reveal the prepared metal oxide pigments are of high purity. Bonding interaction between the alkyd resin and the NPs are studied using Fourier transform infrared spectroscopy (FTIR).The spectral reflectance of the prepared coatings are measured using spectrophotometer in the solar spectrum range, wherein ZnO based nanocoatings shows better results. The cool comfort is measured for ZnO nanocoatings in an enclosed glass cabinet and the differences in temperature with respect to exposure to sunlight are highlighted. Finally, a prototype coated with ZnO NPs maintains lower indoor temperature than the commercially available white paint coated model in the order of 2.7 °C.
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spelling doaj.art-766f0f5165db401a9e59e2f775e8d4852023-08-09T16:11:54ZengIOP PublishingMaterials Research Express2053-15912022-01-019505640410.1088/2053-1591/ac6fbdEnhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatingsV S Benitha0https://orcid.org/0000-0002-9136-5974K Jeyasubramanian1https://orcid.org/0000-0003-4300-4434V S Prabhin2https://orcid.org/0000-0001-9081-7484Department of Electronics and Communication Engineering, Mepco Schlenk Engineering College, Sivakasi - 626 005, IndiaDepartment of Chemistry Mepco Schlenk Engineering College, Sivakasi − 626 005, IndiaDepartment of Electronics and Communication Engineering, V V College of Engineering, Tisaiyanvilai − 627 657, IndiaThe main idea of the research is to formulate alkyd based smart coatings with high NIR-reflectance to decrease the cooling load in order to maintain cool comfort in buildings. In addition to the NIR reflectance studies, the physical characteristics of the coating such as glossiness, hiding power, spreading area, volatile organic contents are evaluated. Heat reflective coatings are prepared by ball milling technique utilizing white metal oxide nanoparticles (NPs) titanium oxide (TiO _2 ), zinc oxide (ZnO) and zirconium oxide (ZrO _2 ) as pigments. The x-ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) results reveal the prepared metal oxide pigments are of high purity. Bonding interaction between the alkyd resin and the NPs are studied using Fourier transform infrared spectroscopy (FTIR).The spectral reflectance of the prepared coatings are measured using spectrophotometer in the solar spectrum range, wherein ZnO based nanocoatings shows better results. The cool comfort is measured for ZnO nanocoatings in an enclosed glass cabinet and the differences in temperature with respect to exposure to sunlight are highlighted. Finally, a prototype coated with ZnO NPs maintains lower indoor temperature than the commercially available white paint coated model in the order of 2.7 °C.https://doi.org/10.1088/2053-1591/ac6fbdmetal oxide nanostructuressolar reflectanceheat reflective paintsthermal comfortthin films
spellingShingle V S Benitha
K Jeyasubramanian
V S Prabhin
Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
Materials Research Express
metal oxide nanostructures
solar reflectance
heat reflective paints
thermal comfort
thin films
title Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
title_full Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
title_fullStr Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
title_full_unstemmed Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
title_short Enhanced near-infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
title_sort enhanced near infrared reflectance and functional characteristics of nano metal oxide embedded alkyd coatings
topic metal oxide nanostructures
solar reflectance
heat reflective paints
thermal comfort
thin films
url https://doi.org/10.1088/2053-1591/ac6fbd
work_keys_str_mv AT vsbenitha enhancednearinfraredreflectanceandfunctionalcharacteristicsofnanometaloxideembeddedalkydcoatings
AT kjeyasubramanian enhancednearinfraredreflectanceandfunctionalcharacteristicsofnanometaloxideembeddedalkydcoatings
AT vsprabhin enhancednearinfraredreflectanceandfunctionalcharacteristicsofnanometaloxideembeddedalkydcoatings