Synthesis and surface active properties of cationic surface active agents from crude rice bran oil

Cationic surfactants of 2-hidroxy-3-(2- alkylamidopolyethyl amino) propane-1-triethylammonium hydroxides (ix-xui)a-d were prepared from fatty acids (i)a-d [palmitic, stearic, oleic, linoleic acid] and mixed fatty acids of crude rice bran oil ie [RBO]. The reaction of these acids with ethylenediamine...

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Main Author: W. I. A. El-Dougdoug
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 1999-10-01
Series:Grasas y Aceites
Subjects:
Online Access:http://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/683
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author W. I. A. El-Dougdoug
author_facet W. I. A. El-Dougdoug
author_sort W. I. A. El-Dougdoug
collection DOAJ
description Cationic surfactants of 2-hidroxy-3-(2- alkylamidopolyethyl amino) propane-1-triethylammonium hydroxides (ix-xui)a-d were prepared from fatty acids (i)a-d [palmitic, stearic, oleic, linoleic acid] and mixed fatty acids of crude rice bran oil ie [RBO]. The reaction of these acids with ethylenediamine, diethylenetriamine, triethylenetetramine andletraethylenepentamine (ii)a-d produced (iii-vii)a-d. The produced amidopolyethylamine (iii-vii)a-d reacted with 2-epoxypropylenetriethylammonium chloride (viii) to give the cationic surfactants (ix-xiii)a-d . The produced derivatives were purified and characterized by microanalysis, molecular weight determination, infra-red (IR), and proton nuclear magnetic resonance (1H NMR) spectra. The surface active properties and inhibition efficiency of the prepared cationic surfactants were determined.
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spelling doaj.art-769e14b4a0ad4181907759fba82e1ea92022-12-21T17:13:29ZengConsejo Superior de Investigaciones CientíficasGrasas y Aceites0017-34951988-42141999-10-0150538539110.3989/gya.1999.v50.i5.683673Synthesis and surface active properties of cationic surface active agents from crude rice bran oilW. I. A. El-Dougdoug0Chemistry Department, Faculty of Science, Zagazig UniversityCationic surfactants of 2-hidroxy-3-(2- alkylamidopolyethyl amino) propane-1-triethylammonium hydroxides (ix-xui)a-d were prepared from fatty acids (i)a-d [palmitic, stearic, oleic, linoleic acid] and mixed fatty acids of crude rice bran oil ie [RBO]. The reaction of these acids with ethylenediamine, diethylenetriamine, triethylenetetramine andletraethylenepentamine (ii)a-d produced (iii-vii)a-d. The produced amidopolyethylamine (iii-vii)a-d reacted with 2-epoxypropylenetriethylammonium chloride (viii) to give the cationic surfactants (ix-xiii)a-d . The produced derivatives were purified and characterized by microanalysis, molecular weight determination, infra-red (IR), and proton nuclear magnetic resonance (1H NMR) spectra. The surface active properties and inhibition efficiency of the prepared cationic surfactants were determined.http://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/683cationic surfactantcrude rice bran oilsurface active propertiessynthesis.
spellingShingle W. I. A. El-Dougdoug
Synthesis and surface active properties of cationic surface active agents from crude rice bran oil
Grasas y Aceites
cationic surfactant
crude rice bran oil
surface active properties
synthesis.
title Synthesis and surface active properties of cationic surface active agents from crude rice bran oil
title_full Synthesis and surface active properties of cationic surface active agents from crude rice bran oil
title_fullStr Synthesis and surface active properties of cationic surface active agents from crude rice bran oil
title_full_unstemmed Synthesis and surface active properties of cationic surface active agents from crude rice bran oil
title_short Synthesis and surface active properties of cationic surface active agents from crude rice bran oil
title_sort synthesis and surface active properties of cationic surface active agents from crude rice bran oil
topic cationic surfactant
crude rice bran oil
surface active properties
synthesis.
url http://grasasyaceites.revistas.csic.es/index.php/grasasyaceites/article/view/683
work_keys_str_mv AT wiaeldougdoug synthesisandsurfaceactivepropertiesofcationicsurfaceactiveagentsfromcrudericebranoil