Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films

Cu(In,Ga)Se<sub>2</sub> (CIGS) thin films were deposited at low temperature (350 °C) and high rate (10 µm/h) by a single stage process. The effect of post-deposition treatments at 400 °C and 500 °C by indium bromide vapor were studied and compared to the effect of a simple annealing unde...

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Main Authors: Deewakar Poudel, Benjamin Belfore, Tasnuva Ashrafee, Shankar Karki, Grace Rajan, Angus Rockett, Sylvain Marsillac
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/13/3596
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author Deewakar Poudel
Benjamin Belfore
Tasnuva Ashrafee
Shankar Karki
Grace Rajan
Angus Rockett
Sylvain Marsillac
author_facet Deewakar Poudel
Benjamin Belfore
Tasnuva Ashrafee
Shankar Karki
Grace Rajan
Angus Rockett
Sylvain Marsillac
author_sort Deewakar Poudel
collection DOAJ
description Cu(In,Ga)Se<sub>2</sub> (CIGS) thin films were deposited at low temperature (350 °C) and high rate (10 µm/h) by a single stage process. The effect of post-deposition treatments at 400 °C and 500 °C by indium bromide vapor were studied and compared to the effect of a simple annealing under selenium. Structural, electrical, and chemical analyses demonstrate that there is a drastic difference between the different types of annealing, with the ones under indium bromide leading to much larger grains and higher conductivity. These properties are associated with a modification of the elemental profiles, specifically for gallium and sodium.
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spelling doaj.art-76b7bc01c3b043c0bb9923d22d5359812023-11-22T01:58:14ZengMDPI AGMaterials1996-19442021-06-011413359610.3390/ma14133596Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin FilmsDeewakar Poudel0Benjamin Belfore1Tasnuva Ashrafee2Shankar Karki3Grace Rajan4Angus Rockett5Sylvain Marsillac6Virginia Institute of Photovoltaics, Old Dominion University, Norfolk, VA 23529, USAVirginia Institute of Photovoltaics, Old Dominion University, Norfolk, VA 23529, USAVirginia Institute of Photovoltaics, Old Dominion University, Norfolk, VA 23529, USAVirginia Institute of Photovoltaics, Old Dominion University, Norfolk, VA 23529, USAVirginia Institute of Photovoltaics, Old Dominion University, Norfolk, VA 23529, USADepartment of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO 80401, USAVirginia Institute of Photovoltaics, Old Dominion University, Norfolk, VA 23529, USACu(In,Ga)Se<sub>2</sub> (CIGS) thin films were deposited at low temperature (350 °C) and high rate (10 µm/h) by a single stage process. The effect of post-deposition treatments at 400 °C and 500 °C by indium bromide vapor were studied and compared to the effect of a simple annealing under selenium. Structural, electrical, and chemical analyses demonstrate that there is a drastic difference between the different types of annealing, with the ones under indium bromide leading to much larger grains and higher conductivity. These properties are associated with a modification of the elemental profiles, specifically for gallium and sodium.https://www.mdpi.com/1996-1944/14/13/3596copper indium gallium selenidepost-deposition treatmentrecrystallizationindium bromide
spellingShingle Deewakar Poudel
Benjamin Belfore
Tasnuva Ashrafee
Shankar Karki
Grace Rajan
Angus Rockett
Sylvain Marsillac
Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films
Materials
copper indium gallium selenide
post-deposition treatment
recrystallization
indium bromide
title Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films
title_full Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films
title_fullStr Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films
title_full_unstemmed Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films
title_short Analysis of Post-Deposition Recrystallization Processing via Indium Bromide of Cu(In,Ga)Se<sub>2</sub> Thin Films
title_sort analysis of post deposition recrystallization processing via indium bromide of cu in ga se sub 2 sub thin films
topic copper indium gallium selenide
post-deposition treatment
recrystallization
indium bromide
url https://www.mdpi.com/1996-1944/14/13/3596
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