Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters

In this paper, we present the results of dispersion of thermodynamically immiscible polypropylene (PP) and ethylene-propylene triple synthetic rubber (EPTSR) polymer blends using the Solution-Enhanced Dispersion by Supercritical Fluid (SEDS) technique at operation conditions in the pressure range of...

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Main Authors: Vener F. Khairutdinov, Ilnar S. Khabriev, Farid M. Gumerov, Rafail M. Khuzakhanov, Ruslan M. Garipov, Talgat R. Akhmetzyanov, Azat N. Ibatullin, Ilmutdin M. Abdulagatov
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/17/6432
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author Vener F. Khairutdinov
Ilnar S. Khabriev
Farid M. Gumerov
Rafail M. Khuzakhanov
Ruslan M. Garipov
Talgat R. Akhmetzyanov
Azat N. Ibatullin
Ilmutdin M. Abdulagatov
author_facet Vener F. Khairutdinov
Ilnar S. Khabriev
Farid M. Gumerov
Rafail M. Khuzakhanov
Ruslan M. Garipov
Talgat R. Akhmetzyanov
Azat N. Ibatullin
Ilmutdin M. Abdulagatov
author_sort Vener F. Khairutdinov
collection DOAJ
description In this paper, we present the results of dispersion of thermodynamically immiscible polypropylene (PP) and ethylene-propylene triple synthetic rubber (EPTSR) polymer blends using the Solution-Enhanced Dispersion by Supercritical Fluid (SEDS) technique at operation conditions in the pressure range of (8 to 25) MPa and at temperatures <i>t</i> = 40 °C and 60 °C. The kinetics of crystallization and phase transformation in polymer blends obtained by conventional method (melt blending) and by mixing in the SEDS process have been studied using the DSC technique. The effects of the SEDS operation process on the physical—chemical (melting temperature, heat of fusion) and mechanical (microparticle size) characteristics of the SEDS-produced polymer blends were studied.
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spelling doaj.art-76cd51fe48e142fca03e4dfcc5047caa2023-11-23T13:06:01ZengMDPI AGEnergies1996-10732022-09-011517643210.3390/en15176432Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating ParametersVener F. Khairutdinov0Ilnar S. Khabriev1Farid M. Gumerov2Rafail M. Khuzakhanov3Ruslan M. Garipov4Talgat R. Akhmetzyanov5Azat N. Ibatullin6Ilmutdin M. Abdulagatov7Chemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaChemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaChemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaChemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaChemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaChemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaChemical Engineering Department, Kazan National Research Technological University, 420015 Kazan, RussiaDepartment of Physical and Organic Chemistry, Dagestan State University, 36700 Makhachkala, RussiaIn this paper, we present the results of dispersion of thermodynamically immiscible polypropylene (PP) and ethylene-propylene triple synthetic rubber (EPTSR) polymer blends using the Solution-Enhanced Dispersion by Supercritical Fluid (SEDS) technique at operation conditions in the pressure range of (8 to 25) MPa and at temperatures <i>t</i> = 40 °C and 60 °C. The kinetics of crystallization and phase transformation in polymer blends obtained by conventional method (melt blending) and by mixing in the SEDS process have been studied using the DSC technique. The effects of the SEDS operation process on the physical—chemical (melting temperature, heat of fusion) and mechanical (microparticle size) characteristics of the SEDS-produced polymer blends were studied.https://www.mdpi.com/1996-1073/15/17/6432heat of fusionkinetic of crystallizationmicroparticle sizeoperating parameterspolymer blendssupercritical fluids
spellingShingle Vener F. Khairutdinov
Ilnar S. Khabriev
Farid M. Gumerov
Rafail M. Khuzakhanov
Ruslan M. Garipov
Talgat R. Akhmetzyanov
Azat N. Ibatullin
Ilmutdin M. Abdulagatov
Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters
Energies
heat of fusion
kinetic of crystallization
microparticle size
operating parameters
polymer blends
supercritical fluids
title Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters
title_full Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters
title_fullStr Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters
title_full_unstemmed Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters
title_short Dispersion of the Thermodynamically Immiscible Polypropylene and Ethylene—Propylene Triple Synthetic Rubber Polymer Blends Using Supercritical SEDS Process: Effect of Operating Parameters
title_sort dispersion of the thermodynamically immiscible polypropylene and ethylene propylene triple synthetic rubber polymer blends using supercritical seds process effect of operating parameters
topic heat of fusion
kinetic of crystallization
microparticle size
operating parameters
polymer blends
supercritical fluids
url https://www.mdpi.com/1996-1073/15/17/6432
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