Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine
Triethylammonium dichloro[N-[(2-oxyphenyl)methylidene]valinato]-phenyl-tin(iv) was prepared and characterized by spectroscopic methods and single crystal X-ray crystallography. The compound consists of a triethylammonium cation and a tin complex as anion. The tin complex is composed of a tridentate...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2023-05-01
|
| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2023-0001 |
| _version_ | 1797810853678940160 |
|---|---|
| author | Böhme Uwe Weling Gisela |
| author_facet | Böhme Uwe Weling Gisela |
| author_sort | Böhme Uwe |
| collection | DOAJ |
| description | Triethylammonium dichloro[N-[(2-oxyphenyl)methylidene]valinato]-phenyl-tin(iv) was prepared and characterized by spectroscopic methods and single crystal X-ray crystallography. The compound consists of a triethylammonium cation and a tin complex as anion. The tin complex is composed of a tridentate O,N,O-Schiff base ligand coordinated to a SnCl2Ph unit. The tin atom is in distorted octahedral coordination geometry. NMR spectroscopic studies have shown that the unusual hexa-coordinated tin complex was formed as a kinetically controlled product. Storage of the solid product for several years led to a transformation into a thermodynamically stable penta-coordinated tin complex. |
| first_indexed | 2024-03-13T07:15:05Z |
| format | Article |
| id | doaj.art-76d65addd4c94d0ca33a7295f9c09bdc |
| institution | Directory Open Access Journal |
| issn | 2191-0219 |
| language | English |
| last_indexed | 2024-03-13T07:15:05Z |
| publishDate | 2023-05-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-76d65addd4c94d0ca33a7295f9c09bdc2023-06-05T09:17:42ZengDe GruyterMain Group Metal Chemistry2191-02192023-05-014619410110.1515/mgmc-2023-0001Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valineBöhme Uwe0Weling Gisela1Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyInstitut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyTriethylammonium dichloro[N-[(2-oxyphenyl)methylidene]valinato]-phenyl-tin(iv) was prepared and characterized by spectroscopic methods and single crystal X-ray crystallography. The compound consists of a triethylammonium cation and a tin complex as anion. The tin complex is composed of a tridentate O,N,O-Schiff base ligand coordinated to a SnCl2Ph unit. The tin atom is in distorted octahedral coordination geometry. NMR spectroscopic studies have shown that the unusual hexa-coordinated tin complex was formed as a kinetically controlled product. Storage of the solid product for several years led to a transformation into a thermodynamically stable penta-coordinated tin complex.https://doi.org/10.1515/mgmc-2023-0001organotinalkyltin complexn-salicylidene-valinecrystal structure |
| spellingShingle | Böhme Uwe Weling Gisela Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine Main Group Metal Chemistry organotin alkyltin complex n-salicylidene-valine crystal structure |
| title | Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine |
| title_full | Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine |
| title_fullStr | Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine |
| title_full_unstemmed | Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine |
| title_short | Synthesis and crystal structure of an ionic phenyltin(iv) complex of N-salicylidene-valine |
| title_sort | synthesis and crystal structure of an ionic phenyltin iv complex of n salicylidene valine |
| topic | organotin alkyltin complex n-salicylidene-valine crystal structure |
| url | https://doi.org/10.1515/mgmc-2023-0001 |
| work_keys_str_mv | AT bohmeuwe synthesisandcrystalstructureofanionicphenyltinivcomplexofnsalicylidenevaline AT welinggisela synthesisandcrystalstructureofanionicphenyltinivcomplexofnsalicylidenevaline |