Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI)
The title compound, [Cu(C12H8N2)2]2[W6O19], consists of two [Cu(phen)2]+ cations (phen = 1,10-phenanthroline) and one typical [W6O19]2− isopolyanion. The CuI atom is coordinated by four N atoms from two bidentate chelating phen ligands in a distorted tetrahedral geometry. The hexatungs...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809020170 |
| _version_ | 1818285304311709696 |
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| author | Zhen-Fang Li Bi-Song Zhang Chang-Sheng Wu |
| author_facet | Zhen-Fang Li Bi-Song Zhang Chang-Sheng Wu |
| author_sort | Zhen-Fang Li |
| collection | DOAJ |
| description | The title compound, [Cu(C12H8N2)2]2[W6O19], consists of two [Cu(phen)2]+ cations (phen = 1,10-phenanthroline) and one typical [W6O19]2− isopolyanion. The CuI atom is coordinated by four N atoms from two bidentate chelating phen ligands in a distorted tetrahedral geometry. The hexatungstate anion, lying on an inversion center and possessing the well known Lindqvist structure, is formed by six edge-sharing WO6 octahedra, thus exhibiting an approximate Oh symmetry. Three kinds of O atoms exist in the hexatungstate, viz. terminal Oa, bridging Ob and central Oc atoms. Besides the electrostatic effects between the anions and cations, weak C—H...O hydrogen bonds exist between the phen ligands and Oa or Ob atoms. The mean interplanar distances of 3.485 (1) and 3.344 (1) Å indicate π–π stacking interactions between neighboring phen ligands. These weak hydrogen bonds and π–π stacking interactions lead to a two-dimensional network. |
| first_indexed | 2024-12-13T01:06:34Z |
| format | Article |
| id | doaj.art-76ebefc49c9147bab2f909d59338ab78 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:06:34Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-76ebefc49c9147bab2f909d59338ab782022-12-22T00:04:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m741m74210.1107/S1600536809020170Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI)Zhen-Fang LiBi-Song ZhangChang-Sheng WuThe title compound, [Cu(C12H8N2)2]2[W6O19], consists of two [Cu(phen)2]+ cations (phen = 1,10-phenanthroline) and one typical [W6O19]2− isopolyanion. The CuI atom is coordinated by four N atoms from two bidentate chelating phen ligands in a distorted tetrahedral geometry. The hexatungstate anion, lying on an inversion center and possessing the well known Lindqvist structure, is formed by six edge-sharing WO6 octahedra, thus exhibiting an approximate Oh symmetry. Three kinds of O atoms exist in the hexatungstate, viz. terminal Oa, bridging Ob and central Oc atoms. Besides the electrostatic effects between the anions and cations, weak C—H...O hydrogen bonds exist between the phen ligands and Oa or Ob atoms. The mean interplanar distances of 3.485 (1) and 3.344 (1) Å indicate π–π stacking interactions between neighboring phen ligands. These weak hydrogen bonds and π–π stacking interactions lead to a two-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536809020170 |
| spellingShingle | Zhen-Fang Li Bi-Song Zhang Chang-Sheng Wu Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI) Acta Crystallographica Section E |
| title | Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI) |
| title_full | Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI) |
| title_fullStr | Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI) |
| title_full_unstemmed | Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI) |
| title_short | Bis[bis(1,10-phenanthroline-κ2N,N′)copper(I)] μ6-oxido-dodecakis-μ2-oxido-hexaoxidohexatungsten(VI) |
| title_sort | bis bis 1 10 phenanthroline amp 954 2n n amp 8242 copper i amp 956 6 oxido dodecakis amp 956 2 oxido hexaoxidohexatungsten vi |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809020170 |
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