Dipotassium disulfanilamidate trihydrate

The asymmetric unit of the title compound, 2K+·2C6H7N2O2S−·3H2O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane....

Full description

Bibliographic Details
Main Authors: Fiona N.-F How, Z. A. Rahima, Hamid Khaledi, Hapipah Mohd Ali
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811026791
_version_ 1818083342489223168
author Fiona N.-F How
Z. A. Rahima
Hamid Khaledi
Hapipah Mohd Ali
author_facet Fiona N.-F How
Z. A. Rahima
Hamid Khaledi
Hapipah Mohd Ali
author_sort Fiona N.-F How
collection DOAJ
description The asymmetric unit of the title compound, 2K+·2C6H7N2O2S−·3H2O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N—H...O, O—H...O, O—H...N and C—H...π interactions. The layers are further linked into a three-dimensional network via N—H...O, N—H...N and O—H...N hydrogen bonds.
first_indexed 2024-12-10T19:36:28Z
format Article
id doaj.art-76f27db5d3974e81913b2bb5775ed3d9
institution Directory Open Access Journal
issn 1600-5368
language English
last_indexed 2024-12-10T19:36:28Z
publishDate 2011-08-01
publisher International Union of Crystallography
record_format Article
series Acta Crystallographica Section E
spelling doaj.art-76f27db5d3974e81913b2bb5775ed3d92022-12-22T01:36:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1071m107110.1107/S1600536811026791Dipotassium disulfanilamidate trihydrateFiona N.-F HowZ. A. RahimaHamid KhalediHapipah Mohd AliThe asymmetric unit of the title compound, 2K+·2C6H7N2O2S−·3H2O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N—H...O, O—H...O, O—H...N and C—H...π interactions. The layers are further linked into a three-dimensional network via N—H...O, N—H...N and O—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811026791
spellingShingle Fiona N.-F How
Z. A. Rahima
Hamid Khaledi
Hapipah Mohd Ali
Dipotassium disulfanilamidate trihydrate
Acta Crystallographica Section E
title Dipotassium disulfanilamidate trihydrate
title_full Dipotassium disulfanilamidate trihydrate
title_fullStr Dipotassium disulfanilamidate trihydrate
title_full_unstemmed Dipotassium disulfanilamidate trihydrate
title_short Dipotassium disulfanilamidate trihydrate
title_sort dipotassium disulfanilamidate trihydrate
url http://scripts.iucr.org/cgi-bin/paper?S1600536811026791
work_keys_str_mv AT fionanfhow dipotassiumdisulfanilamidatetrihydrate
AT zarahima dipotassiumdisulfanilamidatetrihydrate
AT hamidkhaledi dipotassiumdisulfanilamidatetrihydrate
AT hapipahmohdali dipotassiumdisulfanilamidatetrihydrate