Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II)
In the title complex, [Pd(N3)2(C10H9N3)], the PdII ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812013074 |
| _version_ | 1819350348888801280 |
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| author | Kwang Ha |
| author_facet | Kwang Ha |
| author_sort | Kwang Ha |
| collection | DOAJ |
| description | In the title complex, [Pd(N3)2(C10H9N3)], the PdII ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN4 unit, making dihedral angles of 29.02 (9) and 26.47 (9)°. The azide ligands are slightly bent, with N—N—N angles of 173.0 (4) and 174.2 (4)°. In the crystal, molecules are connected by N—H...N and C—H...N hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H...N hydrogen bonds are also observed. |
| first_indexed | 2024-12-24T19:15:00Z |
| format | Article |
| id | doaj.art-770a5a4e0100492aa466ead3707ef3c3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T19:15:00Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-770a5a4e0100492aa466ead3707ef3c32022-12-21T16:42:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m519m51910.1107/S1600536812013074Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II)Kwang HaIn the title complex, [Pd(N3)2(C10H9N3)], the PdII ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN4 unit, making dihedral angles of 29.02 (9) and 26.47 (9)°. The azide ligands are slightly bent, with N—N—N angles of 173.0 (4) and 174.2 (4)°. In the crystal, molecules are connected by N—H...N and C—H...N hydrogen bonds, forming chains along the c axis. When viewed down the b axis, successive chains are stacked in opposite directions. Intramolecular C—H...N hydrogen bonds are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812013074 |
| spellingShingle | Kwang Ha Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II) Acta Crystallographica Section E |
| title | Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II) |
| title_full | Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II) |
| title_fullStr | Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II) |
| title_full_unstemmed | Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II) |
| title_short | Bis(azido-κN)(di-2-pyridylamine-κ2N2,N2′)palladium(II) |
| title_sort | bis azido amp 954 n di 2 pyridylamine amp 954 2n2 n2 amp 8242 palladium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812013074 |
| work_keys_str_mv | AT kwangha bisazidoamp954ndi2pyridylamineamp9542n2n2amp8242palladiumii |