Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel

Abstract The current research of corrosion resistance of stainless steels mainly focuses on characterization of the passive films by point defect mode and mixed-conduction model. The corrosion resistance of the passive films formed on as-received and sensitized AISI304 stainless steel in borate buff...

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Main Authors: Yubo Zhang, Hongyun Luo, Qunpeng Zhong, Honghui Yu, Jinlong Lv
Format: Article
Language:English
Published: SpringerOpen 2019-03-01
Series:Chinese Journal of Mechanical Engineering
Subjects:
Online Access:http://link.springer.com/article/10.1186/s10033-019-0336-8
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author Yubo Zhang
Hongyun Luo
Qunpeng Zhong
Honghui Yu
Jinlong Lv
author_facet Yubo Zhang
Hongyun Luo
Qunpeng Zhong
Honghui Yu
Jinlong Lv
author_sort Yubo Zhang
collection DOAJ
description Abstract The current research of corrosion resistance of stainless steels mainly focuses on characterization of the passive films by point defect mode and mixed-conduction model. The corrosion resistance of the passive films formed on as-received and sensitized AISI304 stainless steel in borate buffer solution were evaluated in this paper. The degree of sensitization and corrosion resistance of AISI304 stainless steels was evaluated by double loop electrochemical potentiodynamic reactivation and electrochemical impedance spectroscopy. The passive films formed on the stainless steels were studied by XPS technique. It was found that as-received specimen had higher pitting corrosion potential and corrosion resistance than sensitized one. The Mott-Schottky results showed that sensitized stainless steel had more defects in the passive film than as-received one. The compositions of the passive films were mainly Cr and Fe oxides according to XPS results.
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spelling doaj.art-77154933025d44a5bad10c4b0c88d1922022-12-22T02:07:50ZengSpringerOpenChinese Journal of Mechanical Engineering1000-93452192-82582019-03-0132111210.1186/s10033-019-0336-8Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless SteelYubo Zhang0Hongyun Luo1Qunpeng Zhong2Honghui Yu3Jinlong Lv4Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beijing University of Aeronautics and AstronauticsKey Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beijing University of Aeronautics and AstronauticsKey Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beijing University of Aeronautics and AstronauticsKey Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beijing University of Aeronautics and AstronauticsChina Waterborne Transport Research InstituteAbstract The current research of corrosion resistance of stainless steels mainly focuses on characterization of the passive films by point defect mode and mixed-conduction model. The corrosion resistance of the passive films formed on as-received and sensitized AISI304 stainless steel in borate buffer solution were evaluated in this paper. The degree of sensitization and corrosion resistance of AISI304 stainless steels was evaluated by double loop electrochemical potentiodynamic reactivation and electrochemical impedance spectroscopy. The passive films formed on the stainless steels were studied by XPS technique. It was found that as-received specimen had higher pitting corrosion potential and corrosion resistance than sensitized one. The Mott-Schottky results showed that sensitized stainless steel had more defects in the passive film than as-received one. The compositions of the passive films were mainly Cr and Fe oxides according to XPS results.http://link.springer.com/article/10.1186/s10033-019-0336-8304 stainless steelSensitizationPassive filmsXPSImpedance
spellingShingle Yubo Zhang
Hongyun Luo
Qunpeng Zhong
Honghui Yu
Jinlong Lv
Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel
Chinese Journal of Mechanical Engineering
304 stainless steel
Sensitization
Passive films
XPS
Impedance
title Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel
title_full Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel
title_fullStr Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel
title_full_unstemmed Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel
title_short Characterization of Passive Films Formed on As-received and Sensitized AISI 304 Stainless Steel
title_sort characterization of passive films formed on as received and sensitized aisi 304 stainless steel
topic 304 stainless steel
Sensitization
Passive films
XPS
Impedance
url http://link.springer.com/article/10.1186/s10033-019-0336-8
work_keys_str_mv AT yubozhang characterizationofpassivefilmsformedonasreceivedandsensitizedaisi304stainlesssteel
AT hongyunluo characterizationofpassivefilmsformedonasreceivedandsensitizedaisi304stainlesssteel
AT qunpengzhong characterizationofpassivefilmsformedonasreceivedandsensitizedaisi304stainlesssteel
AT honghuiyu characterizationofpassivefilmsformedonasreceivedandsensitizedaisi304stainlesssteel
AT jinlonglv characterizationofpassivefilmsformedonasreceivedandsensitizedaisi304stainlesssteel