Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures
In this paper, we demonstrate that trace amounts of P addition can activate the sintering of carbonyl powder and influence the magnetic properties of the sintered materials. Fe-x P (x = 0, 0.6, 0.8, 1.0, 1.2, 1.4, and 1.6 wt.%) samples were fabricated by doping carbonyl powder with different amounts...
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MDPI AG
2019-03-01
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author | Rui Ma Kaiping Yu Litao Liu Heng Jiang Shulong Ye Peng Yu |
author_facet | Rui Ma Kaiping Yu Litao Liu Heng Jiang Shulong Ye Peng Yu |
author_sort | Rui Ma |
collection | DOAJ |
description | In this paper, we demonstrate that trace amounts of P addition can activate the sintering of carbonyl powder and influence the magnetic properties of the sintered materials. Fe-x P (x = 0, 0.6, 0.8, 1.0, 1.2, 1.4, and 1.6 wt.%) samples were fabricated by doping carbonyl powder with different amounts of Fe3P. They were sintered at 1000 °C in argon for 2 h. The sintering of the Fe-0 wt.% P sample was interrupted by the ferrite-austenite transformation at 912 °C due to the low diffusion rate of the austenite. The addition of P can stabilize the ferrite, and suppress the ferrite-austenite transformation. Therefore, all the P-containing samples shrank continuously throughout the whole sintering process, which showed improved sintering densities compared to the P-free sample. However, the sintering density did not increase monotonously with increasing P content. The Fe-1.4 wt.% P and Fe-1.6wt.% P samples easily got oxidized during sintering, and the densification process was thus influenced by the P-containing oxide particles. As a result, the Fe-1.2 wt.% P sample exhibited the highest sintering density (7.664 g/cm3) and the best magnetic properties (coercive force 172 A/m). |
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spelling | doaj.art-7719973bd4bb4c7b90fbe478b0aa20b62022-12-21T21:46:50ZengMDPI AGMetals2075-47012019-03-019332110.3390/met9030321met9030321Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low TemperaturesRui Ma0Kaiping Yu1Litao Liu2Heng Jiang3Shulong Ye4Peng Yu5Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, ChinaDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, ChinaDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, ChinaDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, ChinaDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, ChinaDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, ChinaIn this paper, we demonstrate that trace amounts of P addition can activate the sintering of carbonyl powder and influence the magnetic properties of the sintered materials. Fe-x P (x = 0, 0.6, 0.8, 1.0, 1.2, 1.4, and 1.6 wt.%) samples were fabricated by doping carbonyl powder with different amounts of Fe3P. They were sintered at 1000 °C in argon for 2 h. The sintering of the Fe-0 wt.% P sample was interrupted by the ferrite-austenite transformation at 912 °C due to the low diffusion rate of the austenite. The addition of P can stabilize the ferrite, and suppress the ferrite-austenite transformation. Therefore, all the P-containing samples shrank continuously throughout the whole sintering process, which showed improved sintering densities compared to the P-free sample. However, the sintering density did not increase monotonously with increasing P content. The Fe-1.4 wt.% P and Fe-1.6wt.% P samples easily got oxidized during sintering, and the densification process was thus influenced by the P-containing oxide particles. As a result, the Fe-1.2 wt.% P sample exhibited the highest sintering density (7.664 g/cm3) and the best magnetic properties (coercive force 172 A/m).http://www.mdpi.com/2075-4701/9/3/321diffusionmagnetic propertiessintering behaviorFe-P alloy |
spellingShingle | Rui Ma Kaiping Yu Litao Liu Heng Jiang Shulong Ye Peng Yu Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures Metals diffusion magnetic properties sintering behavior Fe-P alloy |
title | Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures |
title_full | Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures |
title_fullStr | Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures |
title_full_unstemmed | Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures |
title_short | Effects of Fe3P Addition on Sintering Behaviors and Magnetic Properties of Fe-P Alloys Sintered at Low Temperatures |
title_sort | effects of fe3p addition on sintering behaviors and magnetic properties of fe p alloys sintered at low temperatures |
topic | diffusion magnetic properties sintering behavior Fe-P alloy |
url | http://www.mdpi.com/2075-4701/9/3/321 |
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