catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)]
The title complex, [Pr(C7H5O3)2(NO3)(C12H8N2)]·2C12H8N2, has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The PrIII centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one chelating 1,10-p...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812029911 |
| _version_ | 1798031475608649728 |
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| author | Panfeng Wang Dingding Xu Xinqing Wang |
| author_facet | Panfeng Wang Dingding Xu Xinqing Wang |
| author_sort | Panfeng Wang |
| collection | DOAJ |
| description | The title complex, [Pr(C7H5O3)2(NO3)(C12H8N2)]·2C12H8N2, has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The PrIII centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxylate O atoms from four 4-hydroxybenzoate anions and three O atoms from two nitrate anions. The 4-hydroxybenzoate and nitrate anions function as μ2-bridging ligands and link the PrIII ions into a one-dimensional chain structure along the c axis. Intermolecular O—H...N hydrogen bonds are observed between the 4-hydroxybenzoate anions and the uncoordinated 1,10-phenanthroline molecules. |
| first_indexed | 2024-04-11T19:58:09Z |
| format | Article |
| id | doaj.art-771c51ea3dd54d838b5a7c3816ba678f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:58:09Z |
| publishDate | 2012-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-771c51ea3dd54d838b5a7c3816ba678f2022-12-22T04:05:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1148m114810.1107/S1600536812029911catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)]Panfeng WangDingding XuXinqing WangThe title complex, [Pr(C7H5O3)2(NO3)(C12H8N2)]·2C12H8N2, has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The PrIII centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxylate O atoms from four 4-hydroxybenzoate anions and three O atoms from two nitrate anions. The 4-hydroxybenzoate and nitrate anions function as μ2-bridging ligands and link the PrIII ions into a one-dimensional chain structure along the c axis. Intermolecular O—H...N hydrogen bonds are observed between the 4-hydroxybenzoate anions and the uncoordinated 1,10-phenanthroline molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536812029911 |
| spellingShingle | Panfeng Wang Dingding Xu Xinqing Wang catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)] Acta Crystallographica Section E |
| title | catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)] |
| title_full | catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)] |
| title_fullStr | catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)] |
| title_full_unstemmed | catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)] |
| title_short | catena-Poly[[[(1,10-phenanthroline-κ2N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ4O1:O1′-μ-nitrato-κ3O,O′:O] bis(1,10-phenanthroline)] |
| title_sort | catena poly 1 10 phenanthroline amp 954 2n n amp 8242 praseodymium iii di amp 956 4 hydroxybenzoato amp 954 4o1 o1 amp 8242 amp 956 nitrato amp 954 3o o amp 8242 o bis 1 10 phenanthroline |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812029911 |
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