Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites
The aim of the present article is to investigate the influence of the amount of bis(triethoxysilylpropyl) tetrasulfide on the curing characteristics and mechanical and dynamic properties of rubber composites based on epoxidized natural rubber (Epoxyprene 50) filled with 70 phr silica. The obtained r...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2016-07-01
|
| Series: | Science and Engineering of Composite Materials |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/secm-2014-0156 |
| _version_ | 1818584675509075968 |
|---|---|
| author | Al-Hartomy Omar A. Al-Ghamdi Ahmed A. Al Said Said A. Farha Dishovsky Nikolay Mihaylov Mihail |
| author_facet | Al-Hartomy Omar A. Al-Ghamdi Ahmed A. Al Said Said A. Farha Dishovsky Nikolay Mihaylov Mihail |
| author_sort | Al-Hartomy Omar A. |
| collection | DOAJ |
| description | The aim of the present article is to investigate the influence of the amount of bis(triethoxysilylpropyl) tetrasulfide on the curing characteristics and mechanical and dynamic properties of rubber composites based on epoxidized natural rubber (Epoxyprene 50) filled with 70 phr silica. The obtained results showed that although the interaction between the epoxy groups of epoxidized natural rubber and the silanol groups of silica through hydrogen bonds improves the dispersion of filler in the rubber matrix, the presence of silane coupling agents is necessary to obtain rubber compounds and vulcanizates with good vulcanization characteristics and mechanical and dynamic properties. |
| first_indexed | 2024-12-16T08:24:57Z |
| format | Article |
| id | doaj.art-77281d46bea94c239b186d9bbbf18257 |
| institution | Directory Open Access Journal |
| issn | 0792-1233 2191-0359 |
| language | English |
| last_indexed | 2024-12-16T08:24:57Z |
| publishDate | 2016-07-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Science and Engineering of Composite Materials |
| spelling | doaj.art-77281d46bea94c239b186d9bbbf182572022-12-21T22:38:01ZengDe GruyterScience and Engineering of Composite Materials0792-12332191-03592016-07-0123435736210.1515/secm-2014-0156Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based compositesAl-Hartomy Omar A.Al-Ghamdi Ahmed A.0Al Said Said A. FarhaDishovsky Nikolay1Mihaylov Mihail2Faculty of Science, Department of Physics, King Abdulaziz University, 21589 Jeddah, Saudi ArabiaDepartment of Polymer Engineering, University of Chemical Technology and Metallurgy, 1756 Sofia, BulgariaDepartment of Polymer Engineering, University of Chemical Technology and Metallurgy, 1756 Sofia, BulgariaThe aim of the present article is to investigate the influence of the amount of bis(triethoxysilylpropyl) tetrasulfide on the curing characteristics and mechanical and dynamic properties of rubber composites based on epoxidized natural rubber (Epoxyprene 50) filled with 70 phr silica. The obtained results showed that although the interaction between the epoxy groups of epoxidized natural rubber and the silanol groups of silica through hydrogen bonds improves the dispersion of filler in the rubber matrix, the presence of silane coupling agents is necessary to obtain rubber compounds and vulcanizates with good vulcanization characteristics and mechanical and dynamic properties.https://doi.org/10.1515/secm-2014-0156epoxidized natural rubbersilane coupling agentsilica |
| spellingShingle | Al-Hartomy Omar A. Al-Ghamdi Ahmed A. Al Said Said A. Farha Dishovsky Nikolay Mihaylov Mihail Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites Science and Engineering of Composite Materials epoxidized natural rubber silane coupling agent silica |
| title | Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites |
| title_full | Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites |
| title_fullStr | Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites |
| title_full_unstemmed | Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites |
| title_short | Influence of bis(triethoxysilylpropyl) tetrasulfide amount on the properties of silica-filled epoxidized natural rubber-based composites |
| title_sort | influence of bis triethoxysilylpropyl tetrasulfide amount on the properties of silica filled epoxidized natural rubber based composites |
| topic | epoxidized natural rubber silane coupling agent silica |
| url | https://doi.org/10.1515/secm-2014-0156 |
| work_keys_str_mv | AT alhartomyomara influenceofbistriethoxysilylpropyltetrasulfideamountonthepropertiesofsilicafilledepoxidizednaturalrubberbasedcomposites AT alghamdiahmeda influenceofbistriethoxysilylpropyltetrasulfideamountonthepropertiesofsilicafilledepoxidizednaturalrubberbasedcomposites AT alsaidsaidafarha influenceofbistriethoxysilylpropyltetrasulfideamountonthepropertiesofsilicafilledepoxidizednaturalrubberbasedcomposites AT dishovskynikolay influenceofbistriethoxysilylpropyltetrasulfideamountonthepropertiesofsilicafilledepoxidizednaturalrubberbasedcomposites AT mihaylovmihail influenceofbistriethoxysilylpropyltetrasulfideamountonthepropertiesofsilicafilledepoxidizednaturalrubberbasedcomposites |