Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II)
In the title compound, [Zn(C16H16NS2)2(C12H8N2)], the ZnII atom exists within an N2S4 donor set that defines a distorted octahedral geometry; weak intramolecular C—H...S hydrogen bonds are noted. In the crystal, molecules are linked via weak C—H...π interactions, forming C(11) chains propagating alo...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-05-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617007349 |
| _version_ | 1818502102815604736 |
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| author | A. S. Sonia R. Baskaran N. K. Lokanath S. Selvanayagam |
| author_facet | A. S. Sonia R. Baskaran N. K. Lokanath S. Selvanayagam |
| author_sort | A. S. Sonia |
| collection | DOAJ |
| description | In the title compound, [Zn(C16H16NS2)2(C12H8N2)], the ZnII atom exists within an N2S4 donor set that defines a distorted octahedral geometry; weak intramolecular C—H...S hydrogen bonds are noted. In the crystal, molecules are linked via weak C—H...π interactions, forming C(11) chains propagating along [001]. |
| first_indexed | 2024-12-10T21:05:18Z |
| format | Article |
| id | doaj.art-775427db898143758f317e0fb1656971 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-10T21:05:18Z |
| publishDate | 2017-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-775427db898143758f317e0fb16569712022-12-22T01:33:39ZengInternational Union of CrystallographyIUCrData2414-31462017-05-0125x17073410.1107/S2414314617007349tk4032Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II)A. S. Sonia0R. Baskaran1N. K. Lokanath2S. Selvanayagam3Department of Chemistry, Annamalai University, Annamalainagar, Chidambaram 608 002, IndiaDepartment of Chemistry, Annamalai University, Annamalainagar, Chidambaram 608 002, IndiaDepartment of Studies in Physics, University of Mysore, Mysore 570 006, IndiaPG & Research Department of Physics, Government Arts College, Melur 625 106, IndiaIn the title compound, [Zn(C16H16NS2)2(C12H8N2)], the ZnII atom exists within an N2S4 donor set that defines a distorted octahedral geometry; weak intramolecular C—H...S hydrogen bonds are noted. In the crystal, molecules are linked via weak C—H...π interactions, forming C(11) chains propagating along [001].http://scripts.iucr.org/cgi-bin/paper?S2414314617007349crystal structuredithiocarbamatezincweak C—H...π interactionsπ–π interactions |
| spellingShingle | A. S. Sonia R. Baskaran N. K. Lokanath S. Selvanayagam Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II) IUCrData crystal structure dithiocarbamate zinc weak C—H...π interactions π–π interactions |
| title | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II) |
| title_full | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II) |
| title_fullStr | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II) |
| title_full_unstemmed | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II) |
| title_short | Bis[N-benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′](1,10-phenanthroline-κ2N,N′)zinc(II) |
| title_sort | bis n benzyl n 2 phenylethyl dithiocarbamato κ2s s 1 10 phenanthroline κ2n n zinc ii |
| topic | crystal structure dithiocarbamate zinc weak C—H...π interactions π–π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314617007349 |
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