Size control of precipitated particles of amino acids using a bubble column evaporator

The precipitation of five amino acids: DL-alanine, L-arginine, L-leucine, DL-methionine and L-tyrosine was studied at their solubility limits and isoelectric point by using a bubble column evaporator (BCE). The precipitation of amino acids via a bubble column evaporator and a standard stirring metho...

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Main Authors: Atikah Wan Nafi, Mojtaba Taseidifar, Richard M. Pashley, Barry W. Ninham
Format: Article
Language:English
Published: Elsevier 2023-02-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844023007235
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author Atikah Wan Nafi
Mojtaba Taseidifar
Richard M. Pashley
Barry W. Ninham
author_facet Atikah Wan Nafi
Mojtaba Taseidifar
Richard M. Pashley
Barry W. Ninham
author_sort Atikah Wan Nafi
collection DOAJ
description The precipitation of five amino acids: DL-alanine, L-arginine, L-leucine, DL-methionine and L-tyrosine was studied at their solubility limits and isoelectric point by using a bubble column evaporator (BCE). The precipitation of amino acids via a bubble column evaporator and a standard stirring method were compared via turbidity measurements. Particle size, zeta potential and polydispersity index (PDI) were also measured using a Malvern Zeta-sizer and the particle morphology was examined using Scanning Electron Microscopy (SEM). The novel BCE process emerges as a much more effective method than precipitation by standard stirring methods. Better control of fine particle size and growth rates is achieved. The amino acids in zwitterionic form exhibit the same unexplained bubble coalescence inhibition phenomenon as do common salts. This suggests obvious applications in flotation technologies.
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spelling doaj.art-77595722fdbd4301a62db55145750fcc2023-03-02T05:01:56ZengElsevierHeliyon2405-84402023-02-0192e13516Size control of precipitated particles of amino acids using a bubble column evaporatorAtikah Wan Nafi0Mojtaba Taseidifar1Richard M. Pashley2Barry W. Ninham3School of Science, UNSW Canberra, Northcott Drive, Canberra, ACT, 2610, AustraliaSchool of Science, UNSW Canberra, Northcott Drive, Canberra, ACT, 2610, Australia; Corresponding author.School of Science, UNSW Canberra, Northcott Drive, Canberra, ACT, 2610, AustraliaDepartment of Applied Mathematics, Research School of Physical Sciences, The Australian National University, Canberra, ACT, 2600, AustraliaThe precipitation of five amino acids: DL-alanine, L-arginine, L-leucine, DL-methionine and L-tyrosine was studied at their solubility limits and isoelectric point by using a bubble column evaporator (BCE). The precipitation of amino acids via a bubble column evaporator and a standard stirring method were compared via turbidity measurements. Particle size, zeta potential and polydispersity index (PDI) were also measured using a Malvern Zeta-sizer and the particle morphology was examined using Scanning Electron Microscopy (SEM). The novel BCE process emerges as a much more effective method than precipitation by standard stirring methods. Better control of fine particle size and growth rates is achieved. The amino acids in zwitterionic form exhibit the same unexplained bubble coalescence inhibition phenomenon as do common salts. This suggests obvious applications in flotation technologies.http://www.sciencedirect.com/science/article/pii/S2405844023007235PrecipitationAmino acidsSize controlBubble column evaporatorStirring and particle growth rates
spellingShingle Atikah Wan Nafi
Mojtaba Taseidifar
Richard M. Pashley
Barry W. Ninham
Size control of precipitated particles of amino acids using a bubble column evaporator
Heliyon
Precipitation
Amino acids
Size control
Bubble column evaporator
Stirring and particle growth rates
title Size control of precipitated particles of amino acids using a bubble column evaporator
title_full Size control of precipitated particles of amino acids using a bubble column evaporator
title_fullStr Size control of precipitated particles of amino acids using a bubble column evaporator
title_full_unstemmed Size control of precipitated particles of amino acids using a bubble column evaporator
title_short Size control of precipitated particles of amino acids using a bubble column evaporator
title_sort size control of precipitated particles of amino acids using a bubble column evaporator
topic Precipitation
Amino acids
Size control
Bubble column evaporator
Stirring and particle growth rates
url http://www.sciencedirect.com/science/article/pii/S2405844023007235
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AT richardmpashley sizecontrolofprecipitatedparticlesofaminoacidsusingabubblecolumnevaporator
AT barrywninham sizecontrolofprecipitatedparticlesofaminoacidsusingabubblecolumnevaporator