Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology
The epoxidation process of soybean oil (SBO) and peracid produced by 50 wt% hydrogen peroxide (H2O2) and formic acid (FA) was studied with sulfuric acid (H2SO4) as a catalyst. Three reaction parameters, including reaction temperature, FA-to-SBO ratio, and H2O2-to-SBO ratio, were investigated, along...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Sciendo
2023-06-01
|
| Series: | Polish Journal of Chemical Technology |
| Subjects: | |
| Online Access: | https://doi.org/10.2478/pjct-2023-0013 |
| _version_ | 1797788950684762112 |
|---|---|
| author | Zhang Fengyan Dong Yonglu Lin Shudong Gui Xuefeng Hu Jiwen |
| author_facet | Zhang Fengyan Dong Yonglu Lin Shudong Gui Xuefeng Hu Jiwen |
| author_sort | Zhang Fengyan |
| collection | DOAJ |
| description | The epoxidation process of soybean oil (SBO) and peracid produced by 50 wt% hydrogen peroxide (H2O2) and formic acid (FA) was studied with sulfuric acid (H2SO4) as a catalyst. Three reaction parameters, including reaction temperature, FA-to-SBO ratio, and H2O2-to-SBO ratio, were investigated, along with the combined effect on oxirane value (OV). Based on response surface methodology (RSM), the Box-Behnken design (BBD) was used to optimize the process parameters. According to the results, the calculated OV (7.34%) and the experimental OV (7.31%) were signifi cantly in agreement. The product was confi rmed as epoxidized soybean oil (ESO) by IR and NMR characterization methods. These results demonstrated the reliability of RSM to optimize the SBO reaction to produce ESO with high oxygen content. |
| first_indexed | 2024-03-13T01:43:47Z |
| format | Article |
| id | doaj.art-7764fd223be34e6495ced2c37be83765 |
| institution | Directory Open Access Journal |
| issn | 1899-4741 |
| language | English |
| last_indexed | 2024-03-13T01:43:47Z |
| publishDate | 2023-06-01 |
| publisher | Sciendo |
| record_format | Article |
| series | Polish Journal of Chemical Technology |
| spelling | doaj.art-7764fd223be34e6495ced2c37be837652023-07-03T10:21:46ZengSciendoPolish Journal of Chemical Technology1899-47412023-06-01252212910.2478/pjct-2023-0013Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodologyZhang Fengyan0Dong Yonglu1Lin Shudong2Gui Xuefeng3Hu Jiwen41Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R.China6Management Committee of Shaoguan NanXiong Hi-teac Industry Development Zone, Nanxiong512400, P. R.China1Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R.China1Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R.China1Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R.ChinaThe epoxidation process of soybean oil (SBO) and peracid produced by 50 wt% hydrogen peroxide (H2O2) and formic acid (FA) was studied with sulfuric acid (H2SO4) as a catalyst. Three reaction parameters, including reaction temperature, FA-to-SBO ratio, and H2O2-to-SBO ratio, were investigated, along with the combined effect on oxirane value (OV). Based on response surface methodology (RSM), the Box-Behnken design (BBD) was used to optimize the process parameters. According to the results, the calculated OV (7.34%) and the experimental OV (7.31%) were signifi cantly in agreement. The product was confi rmed as epoxidized soybean oil (ESO) by IR and NMR characterization methods. These results demonstrated the reliability of RSM to optimize the SBO reaction to produce ESO with high oxygen content.https://doi.org/10.2478/pjct-2023-0013soybean oilresponse surface methodologyepoxidationoxirane value |
| spellingShingle | Zhang Fengyan Dong Yonglu Lin Shudong Gui Xuefeng Hu Jiwen Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology Polish Journal of Chemical Technology soybean oil response surface methodology epoxidation oxirane value |
| title | Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology |
| title_full | Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology |
| title_fullStr | Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology |
| title_full_unstemmed | Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology |
| title_short | Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology |
| title_sort | optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology |
| topic | soybean oil response surface methodology epoxidation oxirane value |
| url | https://doi.org/10.2478/pjct-2023-0013 |
| work_keys_str_mv | AT zhangfengyan optimizationofproductionprocessofepoxidizedsoybeanoilwithhighoxygencontentthroughresponsesurfacemethodology AT dongyonglu optimizationofproductionprocessofepoxidizedsoybeanoilwithhighoxygencontentthroughresponsesurfacemethodology AT linshudong optimizationofproductionprocessofepoxidizedsoybeanoilwithhighoxygencontentthroughresponsesurfacemethodology AT guixuefeng optimizationofproductionprocessofepoxidizedsoybeanoilwithhighoxygencontentthroughresponsesurfacemethodology AT hujiwen optimizationofproductionprocessofepoxidizedsoybeanoilwithhighoxygencontentthroughresponsesurfacemethodology |