Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks

Poly[[[μ-1,4-bis(pyridin-4-ylmethyl)piperazine][μ-4-(2-carboxylatoethyl)benzoato]copper(II)] monohydrate], a coordination polymer with twofold interpenetrated cds topology networks

The title compound, {[Cu(C10H8O4)(C16H20N4)]·H2O}n, contains square-planar coordinated CuII ions linked by 4-(carboxylatoethyl)benzoato (ceb) and 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold interpenetrating 658 cds topology. Positional c...

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Bibliographic Details
Main Authors: Gabrielle J. Gaskin, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2023-10-01
Series:IUCrData
Subjects:
crystal structure
copper
coordination polymer
disorder
tri-periodic network
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314623008556
Description
Summary:The title compound, {[Cu(C10H8O4)(C16H20N4)]·H2O}n, contains square-planar coordinated CuII ions linked by 4-(carboxylatoethyl)benzoato (ceb) and 1,4-bis(pyridin-4-ylmethyl)piperazine (bpmp) ligands into a tri-periodic coordination polymer with twofold interpenetrating 658 cds topology. Positional crystallographic disorder among the copper atoms, the ethylcarboxy group of the ceb ligands, and the water molecules of crystallization exists in a refined 0.655 (6)/0.345 (6) ratio.
ISSN:2414-3146

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