Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale

To explore the characteristics of nanopores in organic-rich shale, the shale of the Upper Yangtze area under different maturity are studied. Scanning electron microscopy (SEM), low temperature nitrogen experiment (LP-N2-GA) and the Frenkel-Halsey-Hill (FHH) fractal model were used. Results show that...

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Main Authors: Yu Weiming, Tang Hongming
Format: Article
Language:English
Published: De Gruyter 2019-11-01
Series:Nanotechnology Reviews
Subjects:
Online Access:https://doi.org/10.1515/ntrev-2019-0015
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author Yu Weiming
Tang Hongming
author_facet Yu Weiming
Tang Hongming
author_sort Yu Weiming
collection DOAJ
description To explore the characteristics of nanopores in organic-rich shale, the shale of the Upper Yangtze area under different maturity are studied. Scanning electron microscopy (SEM), low temperature nitrogen experiment (LP-N2-GA) and the Frenkel-Halsey-Hill (FHH) fractal model were used. Results show that the intergranular pores and organic pores are most developed, and the pore size is distributed from a few nanometers to several tens of micrometers. The SEM gray scale images make the pore development characteristics of shale be observed more intuitively. Based on the results of low temperature nitrogen adsorption test and FHH fractal model, the results show the fractal dimension of shale is positively correlated with TOC and quartz, but negatively related to clay minerals and feldspar. There is a good relation between maturity and pore volume.With releasing of pressure, the pore evolution gradually returns to the normal compaction trend, and the pore volume of the shale decrease.
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spelling doaj.art-7775f187934c44f79f91f67e448162b72022-12-21T22:32:27ZengDe GruyterNanotechnology Reviews2191-90972019-11-018115616710.1515/ntrev-2019-0015Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shaleYu Weiming0Tang Hongming1School of Geoscience and Technology, Southwest Petroleum University, Chengdu610500, ChinaSchool of Geoscience and Technology, Southwest Petroleum University, Chengdu610500, ChinaTo explore the characteristics of nanopores in organic-rich shale, the shale of the Upper Yangtze area under different maturity are studied. Scanning electron microscopy (SEM), low temperature nitrogen experiment (LP-N2-GA) and the Frenkel-Halsey-Hill (FHH) fractal model were used. Results show that the intergranular pores and organic pores are most developed, and the pore size is distributed from a few nanometers to several tens of micrometers. The SEM gray scale images make the pore development characteristics of shale be observed more intuitively. Based on the results of low temperature nitrogen adsorption test and FHH fractal model, the results show the fractal dimension of shale is positively correlated with TOC and quartz, but negatively related to clay minerals and feldspar. There is a good relation between maturity and pore volume.With releasing of pressure, the pore evolution gradually returns to the normal compaction trend, and the pore volume of the shale decrease.https://doi.org/10.1515/ntrev-2019-0015shalenano-porepore evolutionmaturity
spellingShingle Yu Weiming
Tang Hongming
Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale
Nanotechnology Reviews
shale
nano-pore
pore evolution
maturity
title Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale
title_full Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale
title_fullStr Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale
title_full_unstemmed Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale
title_short Experimental study on the existence of nano-scale pores and the evolution of organic matter in organic-rich shale
title_sort experimental study on the existence of nano scale pores and the evolution of organic matter in organic rich shale
topic shale
nano-pore
pore evolution
maturity
url https://doi.org/10.1515/ntrev-2019-0015
work_keys_str_mv AT yuweiming experimentalstudyontheexistenceofnanoscaleporesandtheevolutionoforganicmatterinorganicrichshale
AT tanghongming experimentalstudyontheexistenceofnanoscaleporesandtheevolutionoforganicmatterinorganicrichshale