Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles

Modification of the physical properties of the (S)-MHPOBC antiferroelectric liquid crystal (AFLC) by doping with low concentrations of gold nanoparticles is presented for the first time. We used several complementary experimental methods to determine the effect of Au nanoparticles on AFLC in the met...

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Main Authors: Sebastian Lalik, Olaf Stefańczyk, Dorota Dardas, Aleksandra Deptuch, Tetiana Yevchenko, Shin-ichi Ohkoshi, Monika Marzec
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/12/3663
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author Sebastian Lalik
Olaf Stefańczyk
Dorota Dardas
Aleksandra Deptuch
Tetiana Yevchenko
Shin-ichi Ohkoshi
Monika Marzec
author_facet Sebastian Lalik
Olaf Stefańczyk
Dorota Dardas
Aleksandra Deptuch
Tetiana Yevchenko
Shin-ichi Ohkoshi
Monika Marzec
author_sort Sebastian Lalik
collection DOAJ
description Modification of the physical properties of the (S)-MHPOBC antiferroelectric liquid crystal (AFLC) by doping with low concentrations of gold nanoparticles is presented for the first time. We used several complementary experimental methods to determine the effect of Au nanoparticles on AFLC in the metal–organic composites. It was found that the dopant inhibits the matrix crystallization process and modifies the phase transitions temperatures and switching time, as well as increases the helical pitch and spontaneous polarization, while the tilt angle slightly changes. We also showed that both the LC matrix and Au nanoparticles show strong fluorescence in the green light range, and the contact angle depends on the temperature and dopant concentration.
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spelling doaj.art-7778b4b79546476d8c8e681f15a2ba812023-11-23T18:09:05ZengMDPI AGMolecules1420-30492022-06-012712366310.3390/molecules27123663Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au NanoparticlesSebastian Lalik0Olaf Stefańczyk1Dorota Dardas2Aleksandra Deptuch3Tetiana Yevchenko4Shin-ichi Ohkoshi5Monika Marzec6Institute of Physics, Jagiellonian University, 30-348 Kraków, PolandDepartment of Chemistry, School of Science, The University of Tokyo, Tokyo 113-0033, JapanInstitute of Molecular Physics, Polish Academy of Sciences, 60-179 Poznań, PolandInstitute of Nuclear Physics, Polish Academy of Sciences, 31-342 Kraków, PolandInstitute of Molecular Physics, Polish Academy of Sciences, 60-179 Poznań, PolandDepartment of Chemistry, School of Science, The University of Tokyo, Tokyo 113-0033, JapanInstitute of Physics, Jagiellonian University, 30-348 Kraków, PolandModification of the physical properties of the (S)-MHPOBC antiferroelectric liquid crystal (AFLC) by doping with low concentrations of gold nanoparticles is presented for the first time. We used several complementary experimental methods to determine the effect of Au nanoparticles on AFLC in the metal–organic composites. It was found that the dopant inhibits the matrix crystallization process and modifies the phase transitions temperatures and switching time, as well as increases the helical pitch and spontaneous polarization, while the tilt angle slightly changes. We also showed that both the LC matrix and Au nanoparticles show strong fluorescence in the green light range, and the contact angle depends on the temperature and dopant concentration.https://www.mdpi.com/1420-3049/27/12/3663antiferroelectric liquid crystalAu nanoparticlesmetal–organic compositeslocalized surface plasmon resonance
spellingShingle Sebastian Lalik
Olaf Stefańczyk
Dorota Dardas
Aleksandra Deptuch
Tetiana Yevchenko
Shin-ichi Ohkoshi
Monika Marzec
Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles
Molecules
antiferroelectric liquid crystal
Au nanoparticles
metal–organic composites
localized surface plasmon resonance
title Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles
title_full Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles
title_fullStr Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles
title_full_unstemmed Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles
title_short Nanocomposites Based on Antiferroelectric Liquid Crystal (S)-MHPOBC Doping with Au Nanoparticles
title_sort nanocomposites based on antiferroelectric liquid crystal s mhpobc doping with au nanoparticles
topic antiferroelectric liquid crystal
Au nanoparticles
metal–organic composites
localized surface plasmon resonance
url https://www.mdpi.com/1420-3049/27/12/3663
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