High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites

Developing insulating materials with minimal environmental impacts and enhanced properties has been the primary challenge in recent years. To address these challenges, date palm fiber (DPF) was treated with a silane coupling agent 3-aminopropyl triethoxysilane and two grafting solvents (acetone and...

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Main Authors: Amal Mlhem, Basim Abu-Jdayil, Muhammad Z. Iqbal
פורמט: Article
שפה:English
יצא לאור: Elsevier 2023-12-01
סדרה:Developments in the Built Environment
נושאים:
גישה מקוונת:http://www.sciencedirect.com/science/article/pii/S2666165923001229
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author Amal Mlhem
Basim Abu-Jdayil
Muhammad Z. Iqbal
author_facet Amal Mlhem
Basim Abu-Jdayil
Muhammad Z. Iqbal
author_sort Amal Mlhem
collection DOAJ
description Developing insulating materials with minimal environmental impacts and enhanced properties has been the primary challenge in recent years. To address these challenges, date palm fiber (DPF) was treated with a silane coupling agent 3-aminopropyl triethoxysilane and two grafting solvents (acetone and ethanol) via the wet chemical method. The treated fibers were used to prepare poly(β-hydroxybutyrate) (PHB)-based composites via melt blending, thermo-compression molding, and annealing. The insulation properties of these green composites revealed that the silylated fiber composites possess an appropriate thermal conductivity, of 0.0901–0.106 W/(m·K). In cold and hot water, the silylated fiber composites drastically decreased water absorption by 20% and 34%, respectively. The tensile strength of the silylated fiber composites reached 18 MPa owing to improved compatibility, and the highest compressive strength was 48.6 MPa with a filler content of 40 wt%. The heat of combustion for silylated fiber composites ranged from 20.79 to 21.94 MJ/kg. The results indicate that silylated DPF-based PHB composites have potential for use in building engineering.
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spelling doaj.art-7784001d8832484a975a556425d5265e2023-12-18T04:25:01ZengElsevierDevelopments in the Built Environment2666-16592023-12-0116100240High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) compositesAmal Mlhem0Basim Abu-Jdayil1Muhammad Z. Iqbal2Chemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab EmiratesChemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates; National Water and Energy Center, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates; Corresponding author. Chemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates.Chemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab EmiratesDeveloping insulating materials with minimal environmental impacts and enhanced properties has been the primary challenge in recent years. To address these challenges, date palm fiber (DPF) was treated with a silane coupling agent 3-aminopropyl triethoxysilane and two grafting solvents (acetone and ethanol) via the wet chemical method. The treated fibers were used to prepare poly(β-hydroxybutyrate) (PHB)-based composites via melt blending, thermo-compression molding, and annealing. The insulation properties of these green composites revealed that the silylated fiber composites possess an appropriate thermal conductivity, of 0.0901–0.106 W/(m·K). In cold and hot water, the silylated fiber composites drastically decreased water absorption by 20% and 34%, respectively. The tensile strength of the silylated fiber composites reached 18 MPa owing to improved compatibility, and the highest compressive strength was 48.6 MPa with a filler content of 40 wt%. The heat of combustion for silylated fiber composites ranged from 20.79 to 21.94 MJ/kg. The results indicate that silylated DPF-based PHB composites have potential for use in building engineering.http://www.sciencedirect.com/science/article/pii/S2666165923001229Green thermal insulatorPolyhydroxybutyrateSilane treatmentDate palm fiberBiodegradable construction material
spellingShingle Amal Mlhem
Basim Abu-Jdayil
Muhammad Z. Iqbal
High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
Developments in the Built Environment
Green thermal insulator
Polyhydroxybutyrate
Silane treatment
Date palm fiber
Biodegradable construction material
title High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
title_full High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
title_fullStr High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
title_full_unstemmed High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
title_short High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
title_sort high performance renewable thermal insulators based on silylated date palm fiber reinforced poly β hydroxybutyrate composites
topic Green thermal insulator
Polyhydroxybutyrate
Silane treatment
Date palm fiber
Biodegradable construction material
url http://www.sciencedirect.com/science/article/pii/S2666165923001229
work_keys_str_mv AT amalmlhem highperformancerenewablethermalinsulatorsbasedonsilylateddatepalmfiberreinforcedpolybhydroxybutyratecomposites
AT basimabujdayil highperformancerenewablethermalinsulatorsbasedonsilylateddatepalmfiberreinforcedpolybhydroxybutyratecomposites
AT muhammadziqbal highperformancerenewablethermalinsulatorsbasedonsilylateddatepalmfiberreinforcedpolybhydroxybutyratecomposites