High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites
Developing insulating materials with minimal environmental impacts and enhanced properties has been the primary challenge in recent years. To address these challenges, date palm fiber (DPF) was treated with a silane coupling agent 3-aminopropyl triethoxysilane and two grafting solvents (acetone and...
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פורמט: | Article |
שפה: | English |
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Elsevier
2023-12-01
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סדרה: | Developments in the Built Environment |
נושאים: | |
גישה מקוונת: | http://www.sciencedirect.com/science/article/pii/S2666165923001229 |
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author | Amal Mlhem Basim Abu-Jdayil Muhammad Z. Iqbal |
author_facet | Amal Mlhem Basim Abu-Jdayil Muhammad Z. Iqbal |
author_sort | Amal Mlhem |
collection | DOAJ |
description | Developing insulating materials with minimal environmental impacts and enhanced properties has been the primary challenge in recent years. To address these challenges, date palm fiber (DPF) was treated with a silane coupling agent 3-aminopropyl triethoxysilane and two grafting solvents (acetone and ethanol) via the wet chemical method. The treated fibers were used to prepare poly(β-hydroxybutyrate) (PHB)-based composites via melt blending, thermo-compression molding, and annealing. The insulation properties of these green composites revealed that the silylated fiber composites possess an appropriate thermal conductivity, of 0.0901–0.106 W/(m·K). In cold and hot water, the silylated fiber composites drastically decreased water absorption by 20% and 34%, respectively. The tensile strength of the silylated fiber composites reached 18 MPa owing to improved compatibility, and the highest compressive strength was 48.6 MPa with a filler content of 40 wt%. The heat of combustion for silylated fiber composites ranged from 20.79 to 21.94 MJ/kg. The results indicate that silylated DPF-based PHB composites have potential for use in building engineering. |
first_indexed | 2024-03-08T22:31:24Z |
format | Article |
id | doaj.art-7784001d8832484a975a556425d5265e |
institution | Directory Open Access Journal |
issn | 2666-1659 |
language | English |
last_indexed | 2024-03-08T22:31:24Z |
publishDate | 2023-12-01 |
publisher | Elsevier |
record_format | Article |
series | Developments in the Built Environment |
spelling | doaj.art-7784001d8832484a975a556425d5265e2023-12-18T04:25:01ZengElsevierDevelopments in the Built Environment2666-16592023-12-0116100240High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) compositesAmal Mlhem0Basim Abu-Jdayil1Muhammad Z. Iqbal2Chemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab EmiratesChemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates; National Water and Energy Center, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates; Corresponding author. Chemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab Emirates.Chemical & Petroleum Engineering Department, United Arab Emirates University, PO Box 15551, Al Ain, United Arab EmiratesDeveloping insulating materials with minimal environmental impacts and enhanced properties has been the primary challenge in recent years. To address these challenges, date palm fiber (DPF) was treated with a silane coupling agent 3-aminopropyl triethoxysilane and two grafting solvents (acetone and ethanol) via the wet chemical method. The treated fibers were used to prepare poly(β-hydroxybutyrate) (PHB)-based composites via melt blending, thermo-compression molding, and annealing. The insulation properties of these green composites revealed that the silylated fiber composites possess an appropriate thermal conductivity, of 0.0901–0.106 W/(m·K). In cold and hot water, the silylated fiber composites drastically decreased water absorption by 20% and 34%, respectively. The tensile strength of the silylated fiber composites reached 18 MPa owing to improved compatibility, and the highest compressive strength was 48.6 MPa with a filler content of 40 wt%. The heat of combustion for silylated fiber composites ranged from 20.79 to 21.94 MJ/kg. The results indicate that silylated DPF-based PHB composites have potential for use in building engineering.http://www.sciencedirect.com/science/article/pii/S2666165923001229Green thermal insulatorPolyhydroxybutyrateSilane treatmentDate palm fiberBiodegradable construction material |
spellingShingle | Amal Mlhem Basim Abu-Jdayil Muhammad Z. Iqbal High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites Developments in the Built Environment Green thermal insulator Polyhydroxybutyrate Silane treatment Date palm fiber Biodegradable construction material |
title | High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites |
title_full | High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites |
title_fullStr | High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites |
title_full_unstemmed | High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites |
title_short | High-performance, renewable thermal insulators based on silylated date palm fiber–reinforced poly(β-hydroxybutyrate) composites |
title_sort | high performance renewable thermal insulators based on silylated date palm fiber reinforced poly β hydroxybutyrate composites |
topic | Green thermal insulator Polyhydroxybutyrate Silane treatment Date palm fiber Biodegradable construction material |
url | http://www.sciencedirect.com/science/article/pii/S2666165923001229 |
work_keys_str_mv | AT amalmlhem highperformancerenewablethermalinsulatorsbasedonsilylateddatepalmfiberreinforcedpolybhydroxybutyratecomposites AT basimabujdayil highperformancerenewablethermalinsulatorsbasedonsilylateddatepalmfiberreinforcedpolybhydroxybutyratecomposites AT muhammadziqbal highperformancerenewablethermalinsulatorsbasedonsilylateddatepalmfiberreinforcedpolybhydroxybutyratecomposites |