Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors

The unique properties of microporous zeolites, including ion-exchange properties, adsorption, molecular sieving, catalysis, conductivity have been exploited in improving the performance of gas sensors. Zeolites have been employed as physical and chemical filters to improve the sensitivity and select...

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Main Authors: Prabir K. Dutta, Xiaogan Li, Yangong Zheng
Format: Article
Language:English
Published: MDPI AG 2012-04-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/12/4/5170
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author Prabir K. Dutta
Xiaogan Li
Yangong Zheng
author_facet Prabir K. Dutta
Xiaogan Li
Yangong Zheng
author_sort Prabir K. Dutta
collection DOAJ
description The unique properties of microporous zeolites, including ion-exchange properties, adsorption, molecular sieving, catalysis, conductivity have been exploited in improving the performance of gas sensors. Zeolites have been employed as physical and chemical filters to improve the sensitivity and selectivity of gas sensors. In addition, direct interaction of gas molecules with the extraframework cations in the nanoconfined space of zeolites has been explored as a basis for developing new impedance-type gas/vapor sensors. In this review, we summarize how these properties of zeolites have been used to develop new sensing paradigms. There is a considerable breadth of transduction processes that have been used for zeolite incorporated sensors, including frequency measurements, optical and the entire gamut of electrochemical measurements. It is clear from the published literature that zeolites provide a route to enhance sensor performance, and it is expected that commercial manifestation of some of the approaches discussed here will take place. The future of zeolite-based sensors will continue to exploit its unique properties and use of other microporous frameworks, including metal organic frameworks. Zeolite composites with electronic materials, including metals will lead to new paradigms in sensing. Use of nano-sized zeolite crystals and zeolite membranes will enhance sensor properties and make possible new routes of miniaturized sensors.
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spelling doaj.art-77901cc4c3d94b64b4ea3f176f4ef81c2022-12-22T03:19:08ZengMDPI AGSensors1424-82202012-04-011245170519410.3390/s120405170Exploitation of Unique Properties of Zeolites in the Development of Gas SensorsPrabir K. DuttaXiaogan LiYangong ZhengThe unique properties of microporous zeolites, including ion-exchange properties, adsorption, molecular sieving, catalysis, conductivity have been exploited in improving the performance of gas sensors. Zeolites have been employed as physical and chemical filters to improve the sensitivity and selectivity of gas sensors. In addition, direct interaction of gas molecules with the extraframework cations in the nanoconfined space of zeolites has been explored as a basis for developing new impedance-type gas/vapor sensors. In this review, we summarize how these properties of zeolites have been used to develop new sensing paradigms. There is a considerable breadth of transduction processes that have been used for zeolite incorporated sensors, including frequency measurements, optical and the entire gamut of electrochemical measurements. It is clear from the published literature that zeolites provide a route to enhance sensor performance, and it is expected that commercial manifestation of some of the approaches discussed here will take place. The future of zeolite-based sensors will continue to exploit its unique properties and use of other microporous frameworks, including metal organic frameworks. Zeolite composites with electronic materials, including metals will lead to new paradigms in sensing. Use of nano-sized zeolite crystals and zeolite membranes will enhance sensor properties and make possible new routes of miniaturized sensors.http://www.mdpi.com/1424-8220/12/4/5170biomedicalcombustionenvironmentalmetal oxidesharsh environment
spellingShingle Prabir K. Dutta
Xiaogan Li
Yangong Zheng
Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors
Sensors
biomedical
combustion
environmental
metal oxides
harsh environment
title Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors
title_full Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors
title_fullStr Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors
title_full_unstemmed Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors
title_short Exploitation of Unique Properties of Zeolites in the Development of Gas Sensors
title_sort exploitation of unique properties of zeolites in the development of gas sensors
topic biomedical
combustion
environmental
metal oxides
harsh environment
url http://www.mdpi.com/1424-8220/12/4/5170
work_keys_str_mv AT prabirkdutta exploitationofuniquepropertiesofzeolitesinthedevelopmentofgassensors
AT xiaoganli exploitationofuniquepropertiesofzeolitesinthedevelopmentofgassensors
AT yangongzheng exploitationofuniquepropertiesofzeolitesinthedevelopmentofgassensors