3,4,5-Trimethoxybenzohydrazidium chloride

The title compound, C10H15N2O4+·Cl−, was obtained as an unexpected by-product during the synthesis of 1-[2-(substituted aryl)]-3-methylpyrazol-5-ones. The hydrazide group is essentially planar, with an r.s.m. deviation of 0.020 (2) Å, and is oriented a...

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Bibliographic Details
Main Authors: Hiroyuki Ishida, Kazuma Gotoh, Hummera Rafique, Amara Mumtaz, Aamer Saeed
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808036301
Description
Summary:The title compound, C10H15N2O4+·Cl−, was obtained as an unexpected by-product during the synthesis of 1-[2-(substituted aryl)]-3-methylpyrazol-5-ones. The hydrazide group is essentially planar, with an r.s.m. deviation of 0.020 (2) Å, and is oriented at a dihedral angle of 30.52 (3)° with respect to the benzene ring. In the crystal structure, the cations and anions are linked through N—H...O and N—H...Cl hydrogen bonds, forming a molecular tape running along the b axis.
ISSN:1600-5368