Reinforcing Mechanisms of Graphene and Nano-TiC in Al<sub>2</sub>O<sub>3</sub>-Based Ceramic-Tool Materials

Graphene and nano-TiC, which have good reinforcing effects on Al<sub>2</sub>O<sub>3</sub>-based ceramic-tool materials, are generally used as additive phases for ceramics. In this study, nine kinds of samples were sintered, to investigate the effects of graphene and nano-TiC...

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Bibliographic Details
Main Authors: Zhefei Sun, Jun Zhao, Xuchao Wang, Enzhao Cui, Hao Yu
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/9/1815
Description
Summary:Graphene and nano-TiC, which have good reinforcing effects on Al<sub>2</sub>O<sub>3</sub>-based ceramic-tool materials, are generally used as additive phases for ceramics. In this study, nine kinds of samples were sintered, to investigate the effects of graphene and nano-TiC on the reinforcing mechanisms of Al<sub>2</sub>O<sub>3</sub>-based ceramics. The experimental results indicated that adding 0.5 vol% graphene and 10 vol% nano-TiC can obtain the optimum flexural strength, fracture toughness, and Vickers hardness, which were 705 ± 44 MPa, 7.4 ± 0.4 MPa m<sup>1/2</sup>, and 20.5 ± 0.8 GPa, respectively. Furthermore, the reinforcing mechanisms of crack bridging, pull-out of graphene, and pull-out of nano-TiC are identified, which are contributed to improving the mechanical properties of ceramics. Meanwhile, other reinforcing mechanisms induced by graphene (graphene break, crack guiding, and 3D propagation) and nano-TiC (crack branching, crack deflection, and peeling) are discussed. These reinforcing mechanisms are coupled together, while decoupling is hard to work out. Thus, further quantitative studies of reinforcing effects of graphene and nano-TiC on Al<sub>2</sub>O<sub>3</sub>-based ceramic-tool materials are necessary to be carried out.
ISSN:2079-4991