Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate
The solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an u...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017007812 |
| _version_ | 1798025909905653760 |
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| author | Bradley M. Wile |
| author_facet | Bradley M. Wile |
| author_sort | Bradley M. Wile |
| collection | DOAJ |
| description | The solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H...Cl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed. |
| first_indexed | 2024-04-11T18:26:30Z |
| format | Article |
| id | doaj.art-77d3573e7a904c0eb8ca28ca2b408292 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T18:26:30Z |
| publishDate | 2017-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-77d3573e7a904c0eb8ca28ca2b4082922022-12-22T04:09:36ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-07-0173793293510.1107/S2056989017007812wm5393Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvateBradley M. Wile0Donald J. Bettinger Department of Chemistry and Biochemistry, Ohio Northern University, 525 S. Main Street, Ada, OH 45810, USAThe solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H...Cl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed.http://scripts.iucr.org/cgi-bin/paper?S2056989017007812crystal structureiminopyridineredox-active ligandcoordination compoundzinc(II)pyridyl halide |
| spellingShingle | Bradley M. Wile Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate Acta Crystallographica Section E: Crystallographic Communications crystal structure iminopyridine redox-active ligand coordination compound zinc(II) pyridyl halide |
| title | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate |
| title_full | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate |
| title_fullStr | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate |
| title_full_unstemmed | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate |
| title_short | Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate |
| title_sort | crystal structure of n 6 bromopyridin 2 yl phenyl methylidene 2 6 dimethylaniline κ2n n dichloridozinc dichloromethane hemisolvate |
| topic | crystal structure iminopyridine redox-active ligand coordination compound zinc(II) pyridyl halide |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017007812 |
| work_keys_str_mv | AT bradleymwile crystalstructureofn6bromopyridin2ylphenylmethylidene26dimethylanilinek2nndichloridozincdichloromethanehemisolvate |