Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate

Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate

The solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an u...

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Bibliographic Details
Main Author:	Bradley M. Wile
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-07-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure iminopyridine redox-active ligand coordination compound zinc(II) pyridyl halide
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989017007812

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