Chemical Activation of a South African Coal using Phosphoric Acid

The potential of a South African coal, Bosjesspruit, as a precursor for a phosphoric acid-activated carbon has been assessed using the adsorption of nitrogen at 77 K and mercury porosimetry. Column cleaning of the coal by froth flotation reduced the ash content from 22 to 12 wt.% and caused maceral...

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Bibliographic Details
Main Authors: François D. Botha, Brian Mcenaney
Format: Article
Language:English
Published: SAGE Publishing 1993-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617499010001-417
Description
Summary:The potential of a South African coal, Bosjesspruit, as a precursor for a phosphoric acid-activated carbon has been assessed using the adsorption of nitrogen at 77 K and mercury porosimetry. Column cleaning of the coal by froth flotation reduced the ash content from 22 to 12 wt.% and caused maceral separtion, resulting in an intertinite-rich product. Reaction of the column-cleaned coal with phosphoric acid in the range 450–550°C produced an activated carbon which was dominantly microporous. The notional BET surface area of the coal reached a maximum of 600 m 2 /g at a reaction temperature of 550°C.
ISSN:0263-6174
2048-4038