Chemical Activation of a South African Coal using Phosphoric Acid
The potential of a South African coal, Bosjesspruit, as a precursor for a phosphoric acid-activated carbon has been assessed using the adsorption of nitrogen at 77 K and mercury porosimetry. Column cleaning of the coal by froth flotation reduced the ash content from 22 to 12 wt.% and caused maceral...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
SAGE Publishing
1993-03-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1177/0263617499010001-417 |
Summary: | The potential of a South African coal, Bosjesspruit, as a precursor for a phosphoric acid-activated carbon has been assessed using the adsorption of nitrogen at 77 K and mercury porosimetry. Column cleaning of the coal by froth flotation reduced the ash content from 22 to 12 wt.% and caused maceral separtion, resulting in an intertinite-rich product. Reaction of the column-cleaned coal with phosphoric acid in the range 450–550°C produced an activated carbon which was dominantly microporous. The notional BET surface area of the coal reached a maximum of 600 m 2 /g at a reaction temperature of 550°C. |
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ISSN: | 0263-6174 2048-4038 |